data_c2 _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'H16 Al Cl4 Cr0.25 Cu4 O26 Pb6 S2 Sb' _chemical_formula_weight 2297.08 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source 'O' 'O' 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Al' 'Al' 0.0645 0.0514 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'S' 'S' 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Cl' 'Cl' 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Cu' 'Cu' 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Sb' 'Sb' -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Pb' 'Pb' -3.3944 10.1111 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Cr' 'Cr' 0.3209 0.6236 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting ? _symmetry_space_group_name_H-M ? loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z' _cell_length_a 18.959(4) _cell_length_b 7.3398(19) _cell_length_c 11.363(3) _cell_angle_alpha 90.00 _cell_angle_beta 112.428(9) _cell_angle_gamma 90.00 _cell_volume 1461.6(6) _cell_formula_units_Z 2 _cell_measurement_temperature 293(2) _cell_measurement_reflns_used ? _cell_measurement_theta_min ? _cell_measurement_theta_max ? _exptl_crystal_description ? _exptl_crystal_colour ? _exptl_crystal_size_max ? _exptl_crystal_size_mid ? _exptl_crystal_size_min ? _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 5.219 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 2004 _exptl_absorpt_coefficient_mu 38.895 _exptl_absorpt_correction_type ? _exptl_absorpt_correction_T_min ? _exptl_absorpt_correction_T_max ? _exptl_absorpt_process_details ? _exptl_special_details ; ? ; _diffrn_ambient_temperature 293(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type ? _diffrn_measurement_method ? _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 8572 _diffrn_reflns_av_R_equivalents 0.0163 _diffrn_reflns_av_sigmaI/netI 0.0230 _diffrn_reflns_limit_h_min -26 _diffrn_reflns_limit_h_max 26 _diffrn_reflns_limit_k_min -10 _diffrn_reflns_limit_k_max 10 _diffrn_reflns_limit_l_min -16 _diffrn_reflns_limit_l_max 16 _diffrn_reflns_theta_min 2.32 _diffrn_reflns_theta_max 30.06 _reflns_number_total 4302 _reflns_number_gt 3878 _reflns_threshold_expression >2sigma(I) _computing_data_collection ? _computing_cell_refinement ? _computing_data_reduction ? _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics ? _computing_publication_material ? _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0156P)^2^+13.8856P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment mixed _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881' _refine_ls_abs_structure_Flack 0.18(6) _refine_ls_number_reflns 4302 _refine_ls_number_parameters 229 _refine_ls_number_restraints 8 _refine_ls_R_factor_all 0.0237 _refine_ls_R_factor_gt 0.0194 _refine_ls_wR_factor_ref 0.0435 _refine_ls_wR_factor_gt 0.0422 _refine_ls_goodness_of_fit_ref 1.053 _refine_ls_restrained_S_all 1.052 _refine_ls_shift/su_max 0.167 _refine_ls_shift/su_mean 0.006 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Pb1 Pb 0.210386(4) -0.00017(6) 0.179202(6) 0.01552(2) Uani 1 1 d . . . Pb21 Pb 0.423141(6) 0.258762(14) 0.203607(10) 0.01675(2) Uani 1 1 d . . . Pb22 Pb -0.423061(6) -0.258839(15) -0.203311(11) 0.01764(3) Uani 1 1 d . . . Cu1 Cu 0.24986(6) 0.25009(16) 0.50024(10) 0.01523(6) Uani 1 1 d . . . Cu2 Cu 0.104335(12) 0.00012(15) 0.36849(2) 0.01309(5) Uani 1 1 d . . . Al Al 0.0000 -0.0005(4) 0.5000 0.01017(15) Uani 0.739(3) 2 d SP . . Cr Cr 0.0000 -0.0005(4) 0.5000 0.01017(15) Uani 0.261(3) 2 d SP . . Sb Sb 0.0000 0.0000 0.0000 0.01058(4) Uani 1 2 d S . . S1 S 0.24971(2) -0.0003(2) -0.09612(4) 0.01166(10) Uani 1 1 d . . . Cl1 Cl 0.36676(3) -0.0001(3) 0.39660(5) 0.03027(15) Uani 1 1 d . . . Cl2 Cl 0.44955(3) 0.0004(2) -0.19868(5) 0.02073(12) Uani 1 1 d . . . O O 0.00284(7) 0.0014(6) -0.17078(11) 0.0120(3) Uani 1 1 d . . . OH1 O 0.23729(8) 0.0011(7) -0.44118(13) 0.0194(4) Uani 1 1 d D . . OH2 O 0.08877(7) 0.0012(7) -0.34600(12) 0.0140(3) Uani 1 1 d D . . OH31 O 0.08249(9) 0.1837(3) 0.04408(17) 0.0178(5) Uani 1 1 d D . . OH32 O -0.08388(10) -0.1834(2) -0.04227(17) 0.0126(5) Uani 1 1 d D . . OH41 O 0.04077(10) 0.1752(3) 0.41670(16) 0.0153(5) Uani 1 1 d D . . OH42 O -0.03878(10) -0.1722(3) -0.41534(17) 0.0130(5) Uani 1 1 d D . . OH51 O 0.17048(9) 0.1838(2) 0.34008(16) 0.0126(4) Uani 1 1 d D . . OH52 O -0.17078(11) -0.1824(3) -0.34029(18) 0.0151(5) Uani 1 1 d D . . OS1 O 0.17665(7) 0.0008(8) -0.07157(12) 0.0206(4) Uani 1 1 d . . . OS2 O 0.31345(8) 0.0015(8) 0.02677(14) 0.0246(4) Uani 1 1 d . . . OS31 O 0.24673(13) 0.1632(3) -0.1732(2) 0.0289(6) Uani 1 1 d . . . OS32 O -0.24951(14) -0.1598(4) 0.1708(2) 0.0340(7) Uani 1 1 d . . . H1 H 0.2372(11) -0.056(3) -0.3644(9) 0.061(14) Uiso 1 1 d D . . H2 H 0.1343(5) 0.056(3) -0.348(2) 0.095(19) Uiso 1 1 d D . . H31 H 0.0718(12) 0.3027(13) 0.0708(19) 0.032(6) Uiso 1 1 d D . . H32 H -0.0680(8) -0.259(2) -0.0976(11) 0.032(6) Uiso 1 1 d D . . H41 H 0.057(2) 0.2634(16) 0.4848(11) 0.042(7) Uiso 1 1 d D . . H42 H -0.0731(10) -0.2625(17) -0.469(2) 0.042(7) Uiso 1 1 d D . . H51 H 0.1326(7) 0.2789(16) 0.302(3) 0.033(7) Uiso 1 1 d D . . H52 H -0.1634(19) -0.2961(13) -0.2934(15) 0.033(7) Uiso 1 1 d D . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Pb1 0.01421(2) 0.01813(3) 0.01466(2) 0.00015(14) 0.00601(2) 0.00006(14) Pb21 0.01857(4) 0.01230(4) 0.01957(4) 0.00001(3) 0.00751(3) -0.00248(3) Pb22 0.01872(4) 0.01216(5) 0.02217(4) -0.00004(4) 0.00795(3) -0.00199(4) Cu1 0.01490(8) 0.01512(10) 0.01439(9) -0.00306(8) 0.00417(7) -0.00479(8) Cu2 0.01237(8) 0.01288(10) 0.01601(8) 0.0014(4) 0.00763(6) 0.0008(4) Al 0.0094(2) 0.0121(3) 0.0088(2) 0.000 0.00321(17) 0.000 Cr 0.0094(2) 0.0121(3) 0.0088(2) 0.000 0.00321(17) 0.000 Sb 0.00907(5) 0.01262(7) 0.00989(6) 0.000 0.00346(4) 0.000 S1 0.01058(15) 0.01243(19) 0.01182(15) 0.0009(6) 0.00411(12) 0.0006(6) Cl1 0.0301(2) 0.0274(3) 0.0237(2) -0.0002(8) -0.0006(2) 0.0004(9) Cl2 0.02336(18) 0.01276(19) 0.02641(19) -0.0018(7) 0.00987(15) -0.0008(7) O 0.0126(5) 0.0158(6) 0.0078(4) 0.0080(14) 0.0040(4) 0.0024(16) OH1 0.0232(6) 0.0154(6) 0.0154(6) -0.0021(18) 0.0027(5) 0.0051(18) OH2 0.0100(5) 0.0178(6) 0.0142(5) 0.0032(17) 0.0046(4) -0.0008(17) OH31 0.0091(6) 0.0241(10) 0.0213(8) -0.0032(7) 0.0071(6) -0.0005(7) OH32 0.0180(7) 0.0051(7) 0.0181(7) -0.0061(6) 0.0107(6) -0.0072(6) OH41 0.0186(7) 0.0166(8) 0.0153(7) -0.0009(6) 0.0115(5) -0.0013(7) OH42 0.0127(7) 0.0079(8) 0.0159(8) -0.0032(7) 0.0027(6) -0.0018(7) OH51 0.0112(6) 0.0117(8) 0.0124(7) 0.0021(6) 0.0017(5) 0.0006(6) OH52 0.0166(8) 0.0125(9) 0.0146(8) 0.0000(7) 0.0043(6) -0.0025(7) OS1 0.0121(5) 0.0349(8) 0.0160(5) -0.0068(18) 0.0067(4) 0.0010(19) OS2 0.0164(6) 0.0309(8) 0.0206(6) -0.002(2) 0.0005(5) -0.005(2) OS31 0.0311(10) 0.0177(9) 0.0325(10) 0.0080(8) 0.0061(8) -0.0068(8) OS32 0.0375(12) 0.0324(12) 0.0239(10) 0.0156(9) 0.0025(9) -0.0118(10) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Pb1 OH52 2.599(2) 2 ? Pb1 OH51 2.606(2) . ? Pb1 OS31 2.610(2) 4_545 ? Pb1 OS32 2.624(3) 3 ? Pb1 OH32 2.6712(17) 2 ? Pb1 OS1 2.6717(16) . ? Pb1 OH31 2.6866(17) . ? Pb1 Cl1 3.0502(8) . ? Pb1 OS2 3.0661(19) . ? Pb1 Cu2 3.4596(7) . ? Pb1 S1 3.4818(10) . ? Pb1 Sb 3.7227(8) . ? Pb21 O 2.383(3) 4 ? Pb21 OH2 2.473(4) 4 ? Pb21 OS1 2.612(4) 4 ? Pb21 OH42 2.6129(17) 4 ? Pb21 OH32 2.778(2) 3 ? Pb21 OS2 2.956(4) . ? Pb21 Cl2 3.0869(13) 2_655 ? Pb21 OS32 3.206(3) 3 ? Pb21 Cl1 3.3689(15) . ? Pb21 S1 3.5077(11) 4 ? Pb21 Pb22 3.5407(9) 2_565 ? Pb21 Al 3.5839(15) 3 ? Pb22 O 2.367(3) 3_445 ? Pb22 OH2 2.462(4) 3_445 ? Pb22 OS1 2.601(4) 3_445 ? Pb22 OH41 2.6392(16) 4_445 ? Pb22 OH31 2.805(2) 3_445 ? Pb22 OS2 2.969(4) 2 ? Pb22 Cl2 3.0906(13) 1_455 ? Pb22 OS31 3.157(3) 3_445 ? Pb22 Cl1 3.3704(15) 2 ? Pb22 S1 3.5084(11) 3_445 ? Pb22 Pb21 3.5407(9) 2_545 ? Pb22 Cr 3.5898(15) 3_444 ? Cu1 OH52 1.9267(19) 3_556 ? Cu1 OH51 1.9298(18) . ? Cu1 OH1 1.990(5) 1_556 ? Cu1 OH1 2.007(5) 4 ? Cu1 Cu2 3.1730(13) . ? Cu1 Cu2 3.1761(13) 4_556 ? Cu1 Cl1 3.4064(19) 4_556 ? Cu1 Cl1 3.4149(19) . ? Cu1 Cu1 3.6699(9) 4_556 ? Cu1 Cu1 3.6699(9) 4_546 ? Cu1 OS32 3.806(3) 3 ? Cu1 Pb1 3.8860(14) 4_556 ? Cu2 OH52 1.948(2) 2 ? Cu2 OH51 1.950(2) . ? Cu2 OH41 1.977(2) . ? Cu2 OH42 1.983(2) 2 ? Cu2 O 2.3859(12) 2 ? Cu2 OH1 2.6214(13) 1_556 ? Cu2 Al 2.8985(6) . ? Cu2 Cu1 3.1761(13) 4_546 ? Cu2 Pb21 3.6795(9) 3_445 ? Al OH42 1.896(3) 1_556 ? Al OH42 1.896(3) 2 ? Al OH2 1.9098(11) 2 ? Al OH2 1.9098(11) 1_556 ? Al OH41 1.927(3) 2_556 ? Al OH41 1.927(3) . ? Al Cu2 2.8985(6) 2_556 ? Al Pb21 3.5839(15) 3_445 ? Al Pb21 3.5839(15) 4_546 ? Al Pb22 3.5898(15) 3_556 ? Al Pb22 3.5898(15) 4_455 ? Sb O 1.9618(14) 2 ? Sb O 1.9618(14) . ? Sb OH31 1.9790(19) 2 ? Sb OH31 1.9790(19) . ? Sb OH32 1.9972(18) . ? Sb OH32 1.9972(18) 2 ? Sb Pb22 3.6290(6) 4_455 ? Sb Pb22 3.6290(6) 3 ? Sb Pb21 3.6309(6) 3_445 ? Sb Pb21 3.6309(6) 4_545 ? Sb Pb1 3.7227(8) 2 ? S1 OS32 1.445(3) 2 ? S1 OS2 1.4570(14) . ? S1 OS31 1.474(3) . ? S1 OS1 1.5136(16) . ? S1 Pb21 3.5077(12) 4_545 ? S1 Pb22 3.5084(12) 3 ? Cl1 Pb22 3.3704(15) 2 ? Cl1 Cu1 3.4064(19) 4_546 ? Cl1 OS32 3.656(3) 3 ? Cl1 OS2 3.929(2) . ? Cl1 Cu2 4.446(2) 4_546 ? Cl1 Cu2 4.448(2) 4_556 ? Cl2 Pb21 3.0869(13) 2_655 ? Cl2 Pb22 3.0907(13) 1_655 ? O Pb22 2.367(3) 3 ? O Pb21 2.383(3) 4_545 ? O Cu2 2.3859(12) 2 ? O OH31 2.687(3) . ? O OH32 2.687(3) 2 ? O OH31 2.874(3) 2 ? O OH42 2.880(3) . ? O OH41 2.891(3) 2 ? O OH32 2.917(3) . ? O OH2 3.016(2) . ? O OS1 3.0489(19) . ? OH1 Cu1 1.990(5) 1_554 ? OH1 Cu1 2.007(5) 4_545 ? OH1 Cu2 2.6214(13) 1_554 ? OH1 H1 0.969(13) . ? OH2 Cr 1.9098(11) 1_554 ? OH2 Al 1.9098(11) 1_554 ? OH2 Pb22 2.462(4) 3 ? OH2 Pb21 2.473(4) 4_545 ? OH2 H2 0.962(13) . ? OH31 Pb22 2.805(2) 3 ? OH31 O 2.874(3) 2 ? OH31 H31 0.971(12) . ? OH32 Pb1 2.6712(17) 2 ? OH32 O 2.687(3) 2 ? OH32 Pb21 2.778(2) 3_445 ? OH32 H32 0.969(13) . ? OH41 Pb22 2.6392(16) 4_455 ? OH41 O 2.891(3) 2 ? OH41 H41 0.965(11) . ? OH42 Cr 1.896(3) 1_554 ? OH42 Al 1.896(3) 1_554 ? OH42 Cu2 1.983(2) 2 ? OH42 Pb21 2.6129(17) 4_545 ? OH42 H42 0.965(13) . ? OH51 OS32 3.090(4) 3 ? OH51 H51 0.976(12) . ? OH52 Cu1 1.9267(19) 3_444 ? OH52 Cu2 1.948(2) 2 ? OH52 Pb1 2.599(2) 2 ? OH52 H52 0.971(11) . ? OS1 OS32 2.400(4) 2 ? OS1 OS2 2.4007(19) . ? OS1 Pb22 2.601(4) 3 ? OS1 Pb21 2.612(4) 4_545 ? OS2 OS32 2.415(4) 2 ? OS2 OS31 2.445(4) . ? OS2 Pb22 2.969(4) 2 ? OS2 OS32 3.431(5) 3 ? OS2 Pb1 4.272(5) 4 ? OS2 Pb1 4.294(5) 4_545 ? OS2 OS2 4.3023(18) 4_545 ? OS31 OS32 2.371(3) 2 ? OS31 Pb1 2.610(2) 4 ? OS31 Pb22 3.157(3) 3 ? OS32 S1 1.445(3) 2 ? OS32 OS31 2.371(3) 2 ? OS32 OS1 2.400(4) 2 ? OS32 OS2 2.415(4) 2 ? OS32 Pb1 2.624(3) 3_445 ? OS32 OH51 3.090(4) 3_445 ? OS32 Pb21 3.206(3) 3_445 ? OS32 OS2 3.431(5) 3_445 ? OS32 Cl1 3.656(3) 3_445 ? OS32 Cu1 3.806(3) 3_445 ? OS32 Pb22 4.310(3) 4_455 ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag OH52 Pb1 OH51 62.19(6) 2 . ? OH52 Pb1 OS31 73.00(8) 2 4_545 ? OH51 Pb1 OS31 133.26(7) . 4_545 ? OH52 Pb1 OS32 132.96(8) 2 3 ? OH51 Pb1 OS32 72.42(8) . 3 ? OS31 Pb1 OS32 143.41(8) 4_545 3 ? OH52 Pb1 OH32 73.41(6) 2 2 ? OH51 Pb1 OH32 103.47(6) . 2 ? OS31 Pb1 OH32 74.19(6) 4_545 2 ? OS32 Pb1 OH32 131.80(6) 3 2 ? OH52 Pb1 OS1 137.46(10) 2 . ? OH51 Pb1 OS1 136.99(10) . . ? OS31 Pb1 OS1 85.70(12) 4_545 . ? OS32 Pb1 OS1 85.03(13) 3 . ? OH32 Pb1 OS1 65.40(8) 2 . ? OH52 Pb1 OH31 102.76(6) 2 . ? OH51 Pb1 OH31 72.56(6) . . ? OS31 Pb1 OH31 133.07(6) 4_545 . ? OS32 Pb1 OH31 73.25(7) 3 . ? OH32 Pb1 OH31 60.39(5) 2 . ? OS1 Pb1 OH31 65.95(8) . . ? OH52 Pb1 Cl1 83.25(5) 2 . ? OH51 Pb1 Cl1 83.36(4) . . ? OS31 Pb1 Cl1 78.76(6) 4_545 . ? OS32 Pb1 Cl1 79.84(6) 3 . ? OH32 Pb1 Cl1 148.34(6) 2 . ? OS1 Pb1 Cl1 128.83(3) . . ? OH31 Pb1 Cl1 148.12(6) . . ? OH52 Pb1 OS2 144.86(11) 2 . ? OH51 Pb1 OS2 144.32(11) . . ? OS31 Pb1 OS2 73.57(12) 4_545 . ? OS32 Pb1 OS2 73.72(13) 3 . ? OH32 Pb1 OS2 107.28(8) 2 . ? OS1 Pb1 OS2 48.88(4) . . ? OH31 Pb1 OS2 107.81(8) . . ? Cl1 Pb1 OS2 79.95(3) . . ? OH52 Pb1 Cu2 33.87(5) 2 . ? OH51 Pb1 Cu2 33.95(5) . . ? OS31 Pb1 Cu2 106.11(6) 4_545 . ? OS32 Pb1 Cu2 105.50(7) 3 . ? OH32 Pb1 Cu2 75.92(5) 2 . ? OS1 Pb1 Cu2 134.72(3) . . ? OH31 Pb1 Cu2 75.11(5) . . ? Cl1 Pb1 Cu2 96.45(2) . . ? OS2 Pb1 Cu2 176.39(3) . . ? OH52 Pb1 S1 148.35(5) 2 . ? OH51 Pb1 S1 148.14(5) . . ? OS31 Pb1 S1 78.51(7) 4_545 . ? OS32 Pb1 S1 78.65(7) 3 . ? OH32 Pb1 S1 85.93(5) 2 . ? OS1 Pb1 S1 24.20(3) . . ? OH31 Pb1 S1 86.71(5) . . ? Cl1 Pb1 S1 104.63(2) . . ? OS2 Pb1 S1 24.68(2) . . ? Cu2 Pb1 S1 158.920(8) . . ? OH52 Pb1 Sb 81.27(4) 2 . ? OH51 Pb1 Sb 81.16(4) . . ? OS31 Pb1 Sb 105.40(5) 4_545 . ? OS32 Pb1 Sb 104.16(5) 3 . ? OH32 Pb1 Sb 31.24(4) 2 . ? OS1 Pb1 Sb 69.27(3) . . ? OH31 Pb1 Sb 30.92(4) . . ? Cl1 Pb1 Sb 161.900(14) . . ? OS2 Pb1 Sb 118.15(3) . . ? Cu2 Pb1 Sb 65.449(18) . . ? S1 Pb1 Sb 93.471(17) . . ? O Pb21 OH2 76.76(10) 4 4 ? O Pb21 OS1 75.08(10) 4 4 ? OH2 Pb21 OS1 70.08(9) 4 4 ? O Pb21 OH42 70.24(5) 4 4 ? OH2 Pb21 OH42 60.79(6) 4 4 ? OS1 Pb21 OH42 124.51(10) 4 4 ? O Pb21 OH32 62.20(5) 4 3 ? OH2 Pb21 OH32 124.53(9) 4 3 ? OS1 Pb21 OH32 64.67(6) 4 3 ? OH42 Pb21 OH32 126.71(6) 4 3 ? O Pb21 OS2 132.41(7) 4 . ? OH2 Pb21 OS2 133.49(7) 4 . ? OS1 Pb21 OS2 82.90(13) 4 . ? OH42 Pb21 OS2 151.08(10) 4 . ? OH32 Pb21 OS2 70.29(7) 3 . ? O Pb21 Cl2 86.85(8) 4 2_655 ? OH2 Pb21 Cl2 136.16(3) 4 2_655 ? OS1 Pb21 Cl2 143.86(4) 4 2_655 ? OH42 Pb21 Cl2 75.44(5) 4 2_655 ? OH32 Pb21 Cl2 79.25(4) 3 2_655 ? OS2 Pb21 Cl2 86.99(8) . 2_655 ? O Pb21 OS32 118.59(8) 4 3 ? OH2 Pb21 OS32 66.29(5) 4 3 ? OS1 Pb21 OS32 47.37(7) 4 3 ? OH42 Pb21 OS32 122.12(7) 4 3 ? OH32 Pb21 OS32 101.51(6) 3 3 ? OS2 Pb21 OS32 67.53(8) . 3 ? Cl2 Pb21 OS32 152.02(5) 2_655 3 ? O Pb21 Cl1 151.08(4) 4 . ? OH2 Pb21 Cl1 81.31(9) 4 . ? OS1 Pb21 Cl1 114.67(6) 4 . ? OH42 Pb21 Cl1 82.71(5) 4 . ? OH32 Pb21 Cl1 146.65(4) 3 . ? OS2 Pb21 Cl1 76.51(6) . . ? Cl2 Pb21 Cl1 96.30(4) 2_655 . ? OS32 Pb21 Cl1 67.51(5) 3 . ? O Pb21 S1 95.54(7) 4 4 ? OH2 Pb21 S1 63.81(4) 4 4 ? OS1 Pb21 S1 23.25(5) 4 4 ? OH42 Pb21 S1 124.55(5) 4 4 ? OH32 Pb21 S1 83.85(4) 3 4 ? OS2 Pb21 S1 76.34(8) . 4 ? Cl2 Pb21 S1 159.474(19) 2_655 4 ? OS32 Pb21 S1 24.33(5) 3 4 ? Cl1 Pb21 S1 91.41(3) . 4 ? O Pb21 Pb22 41.64(8) 4 2_565 ? OH2 Pb21 Pb22 44.02(8) 4 2_565 ? OS1 Pb21 Pb22 47.09(9) 4 2_565 ? OH42 Pb21 Pb22 78.87(4) 4 2_565 ? OH32 Pb21 Pb22 81.17(4) 3 2_565 ? OS2 Pb21 Pb22 129.65(9) . 2_565 ? Cl2 Pb21 Pb22 127.91(3) 2_655 2_565 ? OS32 Pb21 Pb22 79.24(5) 3 2_565 ? Cl1 Pb21 Pb22 124.36(3) . 2_565 ? S1 Pb21 Pb22 59.70(3) 4 2_565 ? O Pb21 Al 74.10(5) 4 3 ? OH2 Pb21 Al 30.25(5) 4 3 ? OS1 Pb21 Al 98.63(8) 4 3 ? OH42 Pb21 Al 30.86(5) 4 3 ? OH32 Pb21 Al 135.72(5) 3 3 ? OS2 Pb21 Al 151.89(4) . 3 ? Cl2 Pb21 Al 106.24(3) 2_655 3 ? OS32 Pb21 Al 92.77(5) 3 3 ? Cl1 Pb21 Al 77.44(4) . 3 ? S1 Pb21 Al 93.99(3) 4 3 ? Pb22 Pb21 Al 60.51(4) 2_565 3 ? O Pb22 OH2 77.26(10) 3_445 3_445 ? O Pb22 OS1 75.54(10) 3_445 3_445 ? OH2 Pb22 OS1 70.43(9) 3_445 3_445 ? O Pb22 OH41 70.29(5) 3_445 4_445 ? OH2 Pb22 OH41 61.39(6) 3_445 4_445 ? OS1 Pb22 OH41 125.34(10) 3_445 4_445 ? O Pb22 OH31 61.92(5) 3_445 3_445 ? OH2 Pb22 OH31 125.07(9) 3_445 3_445 ? OS1 Pb22 OH31 65.17(5) 3_445 3_445 ? OH41 Pb22 OH31 126.05(6) 4_445 3_445 ? O Pb22 OS2 132.62(7) 3_445 2 ? OH2 Pb22 OS2 133.59(7) 3_445 2 ? OS1 Pb22 OS2 83.10(13) 3_445 2 ? OH41 Pb22 OS2 150.17(10) 4_445 2 ? OH31 Pb22 OS2 70.77(7) 3_445 2 ? O Pb22 Cl2 86.61(8) 3_445 1_455 ? OH2 Pb22 Cl2 136.04(4) 3_445 1_455 ? OS1 Pb22 Cl2 143.96(4) 3_445 1_455 ? OH41 Pb22 Cl2 74.71(5) 4_445 1_455 ? OH31 Pb22 Cl2 78.83(4) 3_445 1_455 ? OS2 Pb22 Cl2 86.70(7) 2 1_455 ? O Pb22 OS31 119.32(8) 3_445 3_445 ? OH2 Pb22 OS31 66.19(5) 3_445 3_445 ? OS1 Pb22 OS31 47.76(7) 3_445 3_445 ? OH41 Pb22 OS31 122.42(6) 4_445 3_445 ? OH31 Pb22 OS31 102.56(6) 3_445 3_445 ? OS2 Pb22 OS31 67.76(7) 2 3_445 ? Cl2 Pb22 OS31 151.74(5) 1_455 3_445 ? O Pb22 Cl1 151.05(4) 3_445 2 ? OH2 Pb22 Cl1 80.96(9) 3_445 2 ? OS1 Pb22 Cl1 114.57(6) 3_445 2 ? OH41 Pb22 Cl1 82.63(5) 4_445 2 ? OH31 Pb22 Cl1 146.91(5) 3_445 2 ? OS2 Pb22 Cl1 76.32(6) 2 2 ? Cl2 Pb22 Cl1 96.20(4) 1_455 2 ? OS31 Pb22 Cl1 67.00(5) 3_445 2 ? O Pb22 S1 95.81(7) 3_445 3_445 ? OH2 Pb22 S1 63.87(4) 3_445 3_445 ? OS1 Pb22 S1 23.14(5) 3_445 3_445 ? OH41 Pb22 S1 125.20(5) 4_445 3_445 ? OH31 Pb22 S1 84.43(4) 3_445 3_445 ? OS2 Pb22 S1 76.73(8) 2 3_445 ? Cl2 Pb22 S1 159.579(19) 1_455 3_445 ? OS31 Pb22 S1 24.85(5) 3_445 3_445 ? Cl1 Pb22 S1 91.44(3) 2 3_445 ? O Pb22 Pb21 41.98(8) 3_445 2_545 ? OH2 Pb22 Pb21 44.27(8) 3_445 2_545 ? OS1 Pb22 Pb21 47.35(9) 3_445 2_545 ? OH41 Pb22 Pb21 79.38(4) 4_445 2_545 ? OH31 Pb22 Pb21 81.40(4) 3_445 2_545 ? OS2 Pb22 Pb21 130.11(9) 2 2_545 ? Cl2 Pb22 Pb21 127.99(3) 1_455 2_545 ? OS31 Pb22 Pb21 79.57(4) 3_445 2_545 ? Cl1 Pb22 Pb21 124.27(3) 2 2_545 ? S1 Pb22 Pb21 59.68(3) 3_445 2_545 ? O Pb22 Cr 74.13(5) 3_445 3_444 ? OH2 Pb22 Cr 30.04(5) 3_445 3_444 ? OS1 Pb22 Cr 98.69(8) 3_445 3_444 ? OH41 Pb22 Cr 31.60(5) 4_445 3_444 ? OH31 Pb22 Cr 135.51(5) 3_445 3_444 ? OS2 Pb22 Cr 151.82(4) 2 3_444 ? Cl2 Pb22 Cr 106.26(3) 1_455 3_444 ? OS31 Pb22 Cr 92.54(4) 3_445 3_444 ? Cl1 Pb22 Cr 77.45(4) 2 3_444 ? S1 Pb22 Cr 93.87(3) 3_445 3_444 ? Pb21 Pb22 Cr 60.34(4) 2_545 3_444 ? OH52 Cu1 OH51 179.67(12) 3_556 . ? OH52 Cu1 OH1 94.11(9) 3_556 1_556 ? OH51 Cu1 OH1 86.22(8) . 1_556 ? OH52 Cu1 OH1 85.86(9) 3_556 4 ? OH51 Cu1 OH1 93.82(8) . 4 ? OH1 Cu1 OH1 179.91(11) 1_556 4 ? OH52 Cu1 Cu2 144.97(9) 3_556 . ? OH51 Cu1 Cu2 35.35(6) . . ? OH1 Cu1 Cu2 55.48(5) 1_556 . ? OH1 Cu1 Cu2 124.58(6) 4 . ? OH52 Cu1 Cu2 35.15(7) 3_556 4_556 ? OH51 Cu1 Cu2 144.53(8) . 4_556 ? OH1 Cu1 Cu2 124.57(6) 1_556 4_556 ? OH1 Cu1 Cu2 55.37(5) 4 4_556 ? Cu2 Cu1 Cu2 179.85(5) . 4_556 ? OH52 Cu1 Cl1 85.10(8) 3_556 4_556 ? OH51 Cu1 Cl1 94.89(7) . 4_556 ? OH1 Cu1 Cl1 101.71(9) 1_556 4_556 ? OH1 Cu1 Cl1 78.37(9) 4 4_556 ? Cu2 Cu1 Cl1 84.95(4) . 4_556 ? Cu2 Cu1 Cl1 95.18(4) 4_556 4_556 ? OH52 Cu1 Cl1 94.92(8) 3_556 . ? OH51 Cu1 Cl1 85.09(7) . . ? OH1 Cu1 Cl1 78.34(8) 1_556 . ? OH1 Cu1 Cl1 101.58(9) 4 . ? Cu2 Cu1 Cl1 95.07(4) . . ? Cu2 Cu1 Cl1 84.81(4) 4_556 . ? Cl1 Cu1 Cl1 179.94(7) 4_556 . ? OH52 Cu1 Cu1 75.13(7) 3_556 4_556 ? OH51 Cu1 Cu1 104.58(7) . 4_556 ? OH1 Cu1 Cu1 156.81(10) 1_556 4_556 ? OH1 Cu1 Cu1 23.25(7) 4 4_556 ? Cu2 Cu1 Cu1 125.38(5) . 4_556 ? Cu2 Cu1 Cu1 54.65(3) 4_556 4_556 ? Cl1 Cu1 Cu1 57.56(5) 4_556 4_556 ? Cl1 Cu1 Cu1 122.39(6) . 4_556 ? OH52 Cu1 Cu1 104.92(8) 3_556 4_546 ? OH51 Cu1 Cu1 75.37(7) . 4_546 ? OH1 Cu1 Cu1 23.46(7) 1_556 4_546 ? OH1 Cu1 Cu1 156.48(10) 4 4_546 ? Cu2 Cu1 Cu1 54.73(3) . 4_546 ? Cu2 Cu1 Cu1 125.24(5) 4_556 4_546 ? Cl1 Cu1 Cu1 122.71(6) 4_556 4_546 ? Cl1 Cu1 Cu1 57.34(5) . 4_546 ? Cu1 Cu1 Cu1 179.72(8) 4_556 4_546 ? OH52 Cu1 OS32 125.87(9) 3_556 3 ? OH51 Cu1 OS32 53.86(8) . 3 ? OH1 Cu1 OS32 122.29(9) 1_556 3 ? OH1 Cu1 OS32 57.67(8) 4 3 ? Cu2 Cu1 OS32 87.99(5) . 3 ? Cu2 Cu1 OS32 91.88(5) 4_556 3 ? Cl1 Cu1 OS32 119.40(5) 4_556 3 ? Cl1 Cu1 OS32 60.55(5) . 3 ? Cu1 Cu1 OS32 79.87(5) 4_556 3 ? Cu1 Cu1 OS32 99.89(6) 4_546 3 ? OH52 Cu1 Pb1 36.35(7) 3_556 4_556 ? OH51 Cu1 Pb1 143.66(8) . 4_556 ? OH1 Cu1 Pb1 97.17(8) 1_556 4_556 ? OH1 Cu1 Pb1 82.85(7) 4 4_556 ? Cu2 Cu1 Pb1 122.53(4) . 4_556 ? Cu2 Cu1 Pb1 57.62(2) 4_556 4_556 ? Cl1 Cu1 Pb1 48.91(2) 4_556 4_556 ? Cl1 Cu1 Pb1 131.12(3) . 4_556 ? Cu1 Cu1 Pb1 61.95(3) 4_556 4_556 ? Cu1 Cu1 Pb1 118.25(5) 4_546 4_556 ? OS32 Cu1 Pb1 140.15(5) 3 4_556 ? OH52 Cu2 OH51 87.21(8) 2 . ? OH52 Cu2 OH41 173.64(8) 2 . ? OH51 Cu2 OH41 95.46(10) . . ? OH52 Cu2 OH42 96.67(10) 2 2 ? OH51 Cu2 OH42 173.61(8) . 2 ? OH41 Cu2 OH42 80.18(8) . 2 ? OH52 Cu2 O 102.69(10) 2 2 ? OH51 Cu2 O 102.23(10) . 2 ? OH41 Cu2 O 82.43(9) . 2 ? OH42 Cu2 O 81.92(9) 2 2 ? OH52 Cu2 OH1 70.05(10) 2 1_556 ? OH51 Cu2 OH1 70.01(10) . 1_556 ? OH41 Cu2 OH1 105.41(9) . 1_556 ? OH42 Cu2 OH1 106.50(9) 2 1_556 ? O Cu2 OH1 169.19(5) 2 1_556 ? OH52 Cu2 Al 134.05(9) 2 . ? OH51 Cu2 Al 134.01(9) . . ? OH41 Cu2 Al 41.40(8) . . ? OH42 Cu2 Al 40.52(8) 2 . ? O Cu2 Al 88.96(4) 2 . ? OH1 Cu2 Al 101.84(4) 1_556 . ? OH52 Cu2 Cu1 88.56(6) 2 . ? OH51 Cu2 Cu1 34.92(5) . . ? OH41 Cu2 Cu1 90.33(7) . . ? OH42 Cu2 Cu1 139.76(6) 2 . ? O Cu2 Cu1 135.80(10) 2 . ? OH1 Cu2 Cu1 38.72(10) 1_556 . ? Al Cu2 Cu1 113.53(5) . . ? OH52 Cu2 Cu1 34.72(6) 2 4_546 ? OH51 Cu2 Cu1 88.73(6) . 4_546 ? OH41 Cu2 Cu1 139.36(5) . 4_546 ? OH42 Cu2 Cu1 91.58(7) 2 4_546 ? O Cu2 Cu1 136.08(10) 2 4_546 ? OH1 Cu2 Cu1 39.05(10) 1_556 4_546 ? Al Cu2 Cu1 113.57(5) . 4_546 ? Cu1 Cu2 Cu1 70.622(19) . 4_546 ? OH52 Cu2 Pb1 48.05(6) 2 . ? OH51 Cu2 Pb1 48.28(6) . . ? OH41 Cu2 Pb1 137.15(7) . . ? OH42 Cu2 Pb1 137.64(7) 2 . ? O Cu2 Pb1 84.42(4) 2 . ? OH1 Cu2 Pb1 84.77(4) 1_556 . ? Al Cu2 Pb1 173.382(7) . . ? Cu1 Cu2 Pb1 71.74(3) . . ? Cu1 Cu2 Pb1 71.55(3) 4_546 . ? OH52 Cu2 Pb21 97.00(6) 2 3_445 ? OH51 Cu2 Pb21 141.53(5) . 3_445 ? OH41 Cu2 Pb21 84.52(5) . 3_445 ? OH42 Cu2 Pb21 43.17(5) 2 3_445 ? O Cu2 Pb21 39.48(9) 2 3_445 ? OH1 Cu2 Pb21 146.98(10) 1_556 3_445 ? Al Cu2 Pb21 64.76(3) . 3_445 ? Cu1 Cu2 Pb21 173.45(4) . 3_445 ? Cu1 Cu2 Pb21 115.92(4) 4_546 3_445 ? Pb1 Cu2 Pb21 109.53(2) . 3_445 ? OH42 Al OH42 96.66(17) 1_556 2 ? OH42 Al OH2 95.30(13) 1_556 2 ? OH42 Al OH2 85.19(12) 2 2 ? OH42 Al OH2 85.19(12) 1_556 1_556 ? OH42 Al OH2 95.30(13) 2 1_556 ? OH2 Al OH2 179.3(3) 2 1_556 ? OH42 Al OH41 83.67(8) 1_556 2_556 ? OH42 Al OH41 179.02(8) 2 2_556 ? OH2 Al OH41 93.86(13) 2 2_556 ? OH2 Al OH41 85.65(12) 1_556 2_556 ? OH42 Al OH41 179.02(8) 1_556 . ? OH42 Al OH41 83.67(8) 2 . ? OH2 Al OH41 85.65(13) 2 . ? OH2 Al OH41 93.86(13) 1_556 . ? OH41 Al OH41 96.03(17) 2_556 . ? OH42 Al Cu2 42.81(7) 1_556 2_556 ? OH42 Al Cu2 137.36(13) 2 2_556 ? OH2 Al Cu2 86.34(5) 2 2_556 ? OH2 Al Cu2 93.66(5) 1_556 2_556 ? OH41 Al Cu2 42.71(6) 2_556 2_556 ? OH41 Al Cu2 137.12(12) . 2_556 ? OH42 Al Cu2 137.36(13) 1_556 . ? OH42 Al Cu2 42.81(7) 2 . ? OH2 Al Cu2 93.66(5) 2 . ? OH2 Al Cu2 86.34(5) 1_556 . ? OH41 Al Cu2 137.12(13) 2_556 . ? OH41 Al Cu2 42.71(6) . . ? Cu2 Al Cu2 179.83(11) 2_556 . ? OH42 Al Pb21 92.96(9) 1_556 3_445 ? OH42 Al Pb21 44.99(5) 2 3_445 ? OH2 Al Pb21 40.70(12) 2 3_445 ? OH2 Al Pb21 139.85(14) 1_556 3_445 ? OH41 Al Pb21 134.10(5) 2_556 3_445 ? OH41 Al Pb21 87.92(6) . 3_445 ? Cu2 Al Pb21 111.87(4) 2_556 3_445 ? Cu2 Al Pb21 68.22(3) . 3_445 ? OH42 Al Pb21 44.99(5) 1_556 4_546 ? OH42 Al Pb21 92.96(9) 2 4_546 ? OH2 Al Pb21 139.85(14) 2 4_546 ? OH2 Al Pb21 40.70(12) 1_556 4_546 ? OH41 Al Pb21 87.92(6) 2_556 4_546 ? OH41 Al Pb21 134.10(5) . 4_546 ? Cu2 Al Pb21 68.22(3) 2_556 4_546 ? Cu2 Al Pb21 111.87(4) . 4_546 ? Pb21 Al Pb21 120.91(8) 3_445 4_546 ? OH42 Al Pb22 87.09(6) 1_556 3_556 ? OH42 Al Pb22 135.05(5) 2 3_556 ? OH2 Al Pb22 139.25(14) 2 3_556 ? OH2 Al Pb22 40.19(12) 1_556 3_556 ? OH41 Al Pb22 45.86(5) 2_556 3_556 ? OH41 Al Pb22 92.03(9) . 3_556 ? Cu2 Al Pb22 68.15(3) 2_556 3_556 ? Cu2 Al Pb22 111.76(4) . 3_556 ? Pb21 Al Pb22 179.94(7) 3_445 3_556 ? Pb21 Al Pb22 59.151(18) 4_546 3_556 ? OH42 Al Pb22 135.05(5) 1_556 4_455 ? OH42 Al Pb22 87.09(6) 2 4_455 ? OH2 Al Pb22 40.19(12) 2 4_455 ? OH2 Al Pb22 139.25(14) 1_556 4_455 ? OH41 Al Pb22 92.03(9) 2_556 4_455 ? OH41 Al Pb22 45.86(5) . 4_455 ? Cu2 Al Pb22 111.76(4) 2_556 4_455 ? Cu2 Al Pb22 68.15(3) . 4_455 ? Pb21 Al Pb22 59.151(18) 3_445 4_455 ? Pb21 Al Pb22 179.94(7) 4_546 4_455 ? Pb22 Al Pb22 120.78(8) 3_556 4_455 ? O Sb O 179.4(3) 2 . ? O Sb OH31 85.97(11) 2 2 ? O Sb OH31 93.63(11) . 2 ? O Sb OH31 93.63(11) 2 . ? O Sb OH31 85.97(11) . . ? OH31 Sb OH31 94.12(11) 2 . ? O Sb OH32 85.50(11) 2 . ? O Sb OH32 94.90(11) . . ? OH31 Sb OH32 85.33(7) 2 . ? OH31 Sb OH32 179.00(9) . . ? O Sb OH32 94.90(11) 2 2 ? O Sb OH32 85.50(11) . 2 ? OH31 Sb OH32 179.00(9) 2 2 ? OH31 Sb OH32 85.33(7) . 2 ? OH32 Sb OH32 95.24(11) . 2 ? O Sb Pb22 36.72(11) 2 4_455 ? O Sb Pb22 142.81(11) . 4_455 ? OH31 Sb Pb22 50.07(6) 2 4_455 ? OH31 Sb Pb22 88.70(6) . 4_455 ? OH32 Sb Pb22 90.30(6) . 4_455 ? OH32 Sb Pb22 130.71(6) 2 4_455 ? O Sb Pb22 142.81(11) 2 3 ? O Sb Pb22 36.72(11) . 3 ? OH31 Sb Pb22 88.70(6) 2 3 ? OH31 Sb Pb22 50.07(6) . 3 ? OH32 Sb Pb22 130.71(6) . 3 ? OH32 Sb Pb22 90.30(6) 2 3 ? Pb22 Sb Pb22 121.613(16) 4_455 3 ? O Sb Pb21 37.16(11) 2 3_445 ? O Sb Pb21 143.32(11) . 3_445 ? OH31 Sb Pb21 91.32(6) 2 3_445 ? OH31 Sb Pb21 129.90(6) . 3_445 ? OH32 Sb Pb21 49.33(6) . 3_445 ? OH32 Sb Pb21 89.68(6) 2 3_445 ? Pb22 Sb Pb21 58.380(16) 4_455 3_445 ? Pb22 Sb Pb21 179.961(3) 3 3_445 ? O Sb Pb21 143.32(11) 2 4_545 ? O Sb Pb21 37.16(11) . 4_545 ? OH31 Sb Pb21 129.90(6) 2 4_545 ? OH31 Sb Pb21 91.32(6) . 4_545 ? OH32 Sb Pb21 89.68(6) . 4_545 ? OH32 Sb Pb21 49.33(6) 2 4_545 ? Pb22 Sb Pb21 179.961(3) 4_455 4_545 ? Pb22 Sb Pb21 58.380(16) 3 4_545 ? Pb21 Sb Pb21 121.627(16) 3_445 4_545 ? O Sb Pb1 96.49(4) 2 2 ? O Sb Pb1 83.51(4) . 2 ? OH31 Sb Pb1 44.23(5) 2 2 ? OH31 Sb Pb1 135.81(5) . 2 ? OH32 Sb Pb1 43.91(5) . 2 ? OH32 Sb Pb1 136.05(5) 2 2 ? Pb22 Sb Pb1 75.010(15) 4_455 2 ? Pb22 Sb Pb1 105.009(15) 3 2 ? Pb21 Sb Pb1 75.028(15) 3_445 2 ? Pb21 Sb Pb1 104.952(15) 4_545 2 ? O Sb Pb1 83.51(4) 2 . ? O Sb Pb1 96.49(4) . . ? OH31 Sb Pb1 135.81(5) 2 . ? OH31 Sb Pb1 44.23(5) . . ? OH32 Sb Pb1 136.05(5) . . ? OH32 Sb Pb1 43.91(5) 2 . ? Pb22 Sb Pb1 105.009(15) 4_455 . ? Pb22 Sb Pb1 75.010(15) 3 . ? Pb21 Sb Pb1 104.952(15) 3_445 . ? Pb21 Sb Pb1 75.028(15) 4_545 . ? Pb1 Sb Pb1 179.961(13) 2 . ? OS32 S1 OS2 112.7(2) 2 . ? OS32 S1 OS31 108.64(14) 2 . ? OS2 S1 OS31 113.1(2) . . ? OS32 S1 OS1 108.4(2) 2 . ? OS2 S1 OS1 107.82(9) . . ? OS31 S1 OS1 106.0(2) . . ? OS32 S1 Pb1 125.06(13) 2 . ? OS2 S1 Pb1 61.48(7) . . ? OS31 S1 Pb1 124.13(12) . . ? OS1 S1 Pb1 46.35(5) . . ? OS32 S1 Pb21 66.07(12) 2 4_545 ? OS2 S1 Pb21 131.41(17) . 4_545 ? OS31 S1 Pb21 112.63(8) . 4_545 ? OS1 S1 Pb21 42.94(16) . 4_545 ? Pb1 S1 Pb21 79.70(2) . 4_545 ? OS32 S1 Pb22 114.36(9) 2 3 ? OS2 S1 Pb22 130.64(18) . 3 ? OS31 S1 Pb22 64.12(10) . 3 ? OS1 S1 Pb22 42.48(16) . 3 ? Pb1 S1 Pb22 79.64(2) . 3 ? Pb21 S1 Pb22 60.617(18) 4_545 3 ? Pb1 Cl1 Pb21 85.68(3) . . ? Pb1 Cl1 Pb22 85.62(3) . 2 ? Pb21 Cl1 Pb22 68.63(2) . 2 ? Pb1 Cl1 Cu1 73.77(3) . 4_546 ? Pb21 Cl1 Cu1 159.45(2) . 4_546 ? Pb22 Cl1 Cu1 109.23(7) 2 4_546 ? Pb1 Cl1 Cu1 73.82(3) . . ? Pb21 Cl1 Cu1 109.28(7) . . ? Pb22 Cl1 Cu1 159.44(2) 2 . ? Cu1 Cl1 Cu1 65.10(2) 4_546 . ? Pb1 Cl1 OS32 44.95(4) . 3 ? Pb21 Cl1 OS32 54.13(5) . 3 ? Pb22 Cl1 OS32 100.59(5) 2 3 ? Cu1 Cl1 OS32 108.21(5) 4_546 3 ? Cu1 Cl1 OS32 65.03(6) . 3 ? Pb1 Cl1 OS2 50.20(3) . . ? Pb21 Cl1 OS2 47.02(7) . . ? Pb22 Cl1 OS2 47.23(7) 2 . ? Cu1 Cl1 OS2 115.70(7) 4_546 . ? Cu1 Cl1 OS2 115.55(7) . . ? OS32 Cl1 OS2 53.64(9) 3 . ? Pb1 Cl1 Cu2 110.19(5) . 4_546 ? Pb21 Cl1 Cu2 149.21(4) . 4_546 ? Pb22 Cl1 Cu2 85.94(5) 2 4_546 ? Cu1 Cl1 Cu2 45.31(3) 4_546 4_546 ? Cu1 Cl1 Cu2 100.61(3) . 4_546 ? OS32 Cl1 Cu2 152.66(5) 3 4_546 ? OS2 Cl1 Cu2 124.54(10) . 4_546 ? Pb1 Cl1 Cu2 110.20(5) . 4_556 ? Pb21 Cl1 Cu2 85.88(5) . 4_556 ? Pb22 Cl1 Cu2 149.21(4) 2 4_556 ? Cu1 Cl1 Cu2 100.68(3) 4_546 4_556 ? Cu1 Cl1 Cu2 45.32(3) . 4_556 ? OS32 Cl1 Cu2 76.15(6) 3 4_556 ? OS2 Cl1 Cu2 124.18(10) . 4_556 ? Cu2 Cl1 Cu2 111.22(2) 4_546 4_556 ? Pb21 Cl2 Pb22 75.90(2) 2_655 1_655 ? Sb O Pb22 113.59(14) . 3 ? Sb O Pb21 113.02(14) . 4_545 ? Pb22 O Pb21 96.38(5) 3 4_545 ? Sb O Cu2 126.62(7) . 2 ? Pb22 O Cu2 101.47(10) 3 2 ? Pb21 O Cu2 100.99(11) 4_545 2 ? Sb O OH31 47.29(7) . . ? Pb22 O OH31 67.07(10) 3 . ? Pb21 O OH31 110.73(7) 4_545 . ? Cu2 O OH31 147.04(18) 2 . ? Sb O OH32 47.81(7) . 2 ? Pb22 O OH32 110.27(6) 3 2 ? Pb21 O OH32 66.14(9) 4_545 2 ? Cu2 O OH32 146.62(18) 2 2 ? OH31 O OH32 60.19(6) . 2 ? Sb O OH31 43.42(6) . 2 ? Pb22 O OH31 102.30(15) 3 2 ? Pb21 O OH31 154.70(13) 4_545 2 ? Cu2 O OH31 91.92(7) 2 2 ? OH31 O OH31 62.71(9) . 2 ? OH32 O OH31 91.22(7) 2 2 ? Sb O OH42 148.36(18) . . ? Pb22 O OH42 97.97(7) 3 . ? Pb21 O OH42 58.62(7) 4_545 . ? Cu2 O OH42 42.98(5) 2 . ? OH31 O OH42 161.66(9) . . ? OH32 O OH42 119.86(16) 2 . ? OH31 O OH42 133.63(6) 2 . ? Sb O OH41 148.52(18) . 2 ? Pb22 O OH41 59.26(7) 3 2 ? Pb21 O OH41 98.44(7) 4_545 2 ? Cu2 O OH41 42.67(5) 2 2 ? OH31 O OH41 120.86(16) . 2 ? OH32 O OH41 161.41(9) 2 2 ? OH31 O OH41 105.71(12) 2 2 ? OH42 O OH41 52.44(6) . 2 ? Sb O OH32 43.02(6) . . ? Pb22 O OH32 154.87(13) 3 . ? Pb21 O OH32 102.06(15) 4_545 . ? Cu2 O OH32 91.69(7) 2 . ? OH31 O OH32 90.31(7) . . ? OH32 O OH32 63.39(9) 2 . ? OH31 O OH32 55.47(6) 2 . ? OH42 O OH32 106.15(12) . . ? OH41 O OH32 132.94(6) 2 . ? Sb O OH2 151.49(6) . . ? Pb22 O OH2 52.77(9) 3 . ? Pb21 O OH2 52.96(9) 4_545 . ? Cu2 O OH2 81.89(5) 2 . ? OH31 O OH2 110.02(10) . . ? OH32 O OH2 109.11(10) 2 . ? OH31 O OH2 151.67(19) 2 . ? OH42 O OH2 51.75(8) . . ? OH41 O OH2 52.36(7) 2 . ? OH32 O OH2 151.65(19) . . ? Sb O OS1 93.89(5) . . ? Pb22 O OS1 55.71(10) 3 . ? Pb21 O OS1 55.87(10) 4_545 . ? Cu2 O OS1 139.48(6) 2 . ? OH31 O OS1 60.73(8) . . ? OH32 O OS1 60.03(8) 2 . ? OH31 O OS1 123.43(11) 2 . ? OH42 O OS1 102.46(9) . . ? OH41 O OS1 103.19(9) 2 . ? OH32 O OS1 123.40(11) . . ? OH2 O OS1 57.60(4) . . ? Cu1 OH1 Cu1 133.30(9) 1_554 4_545 ? Cu1 OH1 Cu2 85.80(10) 1_554 1_554 ? Cu1 OH1 Cu2 85.57(10) 4_545 1_554 ? Cu1 OH1 H1 137.8(11) 1_554 . ? Cu1 OH1 H1 86.9(12) 4_545 . ? Cu2 OH1 H1 114.2(11) 1_554 . ? Cr OH2 Al 0.0 1_554 1_554 ? Cr OH2 Pb22 109.77(16) 1_554 3 ? Al OH2 Pb22 109.77(16) 1_554 3 ? Cr OH2 Pb21 109.05(16) 1_554 4_545 ? Al OH2 Pb21 109.05(16) 1_554 4_545 ? Pb22 OH2 Pb21 91.71(5) 3 4_545 ? Cr OH2 O 95.49(6) 1_554 . ? Al OH2 O 95.49(6) 1_554 . ? Pb22 OH2 O 49.97(9) 3 . ? Pb21 OH2 O 50.29(9) 4_545 . ? Cr OH2 H2 117.6(12) 1_554 . ? Al OH2 H2 117.6(12) 1_554 . ? Pb22 OH2 H2 91.6(14) 3 . ? Pb21 OH2 H2 128.8(11) 4_545 . ? O OH2 H2 137.3(14) . . ? Sb OH31 Pb1 104.85(8) . . ? Sb OH31 O 46.75(6) . . ? Pb1 OH31 O 109.94(10) . . ? Sb OH31 Pb22 97.18(7) . 3 ? Pb1 OH31 Pb22 109.20(7) . 3 ? O OH31 Pb22 51.02(7) . 3 ? Sb OH31 O 42.95(6) . 2 ? Pb1 OH31 O 92.16(8) . 2 ? O OH31 O 89.70(11) . 2 ? Pb22 OH31 O 139.40(7) 3 2 ? Sb OH31 H31 116.9(13) . . ? Pb1 OH31 H31 121.6(11) . . ? O OH31 H31 128.3(11) . . ? Pb22 OH31 H31 104.2(12) 3 . ? O OH31 H31 92.2(13) 2 . ? Sb OH32 Pb1 104.85(7) . 2 ? Sb OH32 O 46.70(6) . 2 ? Pb1 OH32 O 110.38(10) 2 2 ? Sb OH32 Pb21 97.64(6) . 3_445 ? Pb1 OH32 Pb21 110.52(7) 2 3_445 ? O OH32 Pb21 51.66(7) 2 3_445 ? Sb OH32 O 42.08(6) . . ? Pb1 OH32 O 91.52(7) 2 . ? O OH32 O 88.78(11) 2 . ? Pb21 OH32 O 138.99(7) 3_445 . ? Sb OH32 H32 97.2(9) . . ? Pb1 OH32 H32 110.0(7) 2 . ? O OH32 H32 131.4(8) 2 . ? Pb21 OH32 H32 131.1(8) 3_445 . ? O OH32 H32 64.3(10) . . ? Al OH41 Cu2 95.89(11) . . ? Al OH41 Pb22 102.53(7) . 4_455 ? Cu2 OH41 Pb22 104.83(7) . 4_455 ? Al OH41 O 99.16(11) . 2 ? Cu2 OH41 O 54.90(7) . 2 ? Pb22 OH41 O 50.44(6) 4_455 2 ? Al OH41 H41 97.0(17) . . ? Cu2 OH41 H41 128(2) . . ? Pb22 OH41 H41 120.9(16) 4_455 . ? O OH41 H41 163.2(12) 2 . ? Cr OH42 Al 0.00(12) 1_554 1_554 ? Cr OH42 Cu2 96.67(10) 1_554 2 ? Al OH42 Cu2 96.67(10) 1_554 2 ? Cr OH42 Pb21 104.15(7) 1_554 4_545 ? Al OH42 Pb21 104.15(7) 1_554 4_545 ? Cu2 OH42 Pb21 105.55(8) 2 4_545 ? Cr OH42 O 100.31(11) 1_554 . ? Al OH42 O 100.31(11) 1_554 . ? Cu2 OH42 O 55.10(7) 2 . ? Pb21 OH42 O 51.14(7) 4_545 . ? Cr OH42 H42 115.7(14) 1_554 . ? Al OH42 H42 115.7(14) 1_554 . ? Cu2 OH42 H42 105.5(12) 2 . ? Pb21 OH42 H42 125.2(10) 4_545 . ? O OH42 H42 141.6(15) . . ? Cu1 OH51 Cu2 109.73(10) . . ? Cu1 OH51 Pb1 117.48(9) . . ? Cu2 OH51 Pb1 97.76(7) . . ? Cu1 OH51 OS32 95.85(9) . 3 ? Cu2 OH51 OS32 149.25(10) . 3 ? Pb1 OH51 OS32 54.05(6) . 3 ? Cu1 OH51 H51 114.3(14) . . ? Cu2 OH51 H51 98.9(11) . . ? Pb1 OH51 H51 115(2) . . ? OS32 OH51 H51 85.2(17) 3 . ? Cu1 OH52 Cu2 110.13(11) 3_444 2 ? Cu1 OH52 Pb1 117.58(10) 3_444 2 ? Cu2 OH52 Pb1 98.08(8) 2 2 ? Cu1 OH52 H52 101.1(12) 3_444 . ? Cu2 OH52 H52 136(2) 2 . ? Pb1 OH52 H52 94.3(15) 2 . ? S1 OS1 OS32 34.86(12) . 2 ? S1 OS1 OS2 35.30(5) . . ? OS32 OS1 OS2 60.42(11) 2 . ? S1 OS1 Pb22 114.4(2) . 3 ? OS32 OS1 Pb22 119.01(9) 2 3 ? OS2 OS1 Pb22 133.3(2) . 3 ? S1 OS1 Pb21 113.8(2) . 4_545 ? OS32 OS1 Pb21 79.43(14) 2 4_545 ? OS2 OS1 Pb21 133.3(2) . 4_545 ? Pb22 OS1 Pb21 85.56(4) 3 4_545 ? S1 OS1 Pb1 109.45(6) . . ? OS32 OS1 Pb1 123.60(13) 2 . ? OS2 OS1 Pb1 74.16(5) . . ? Pb22 OS1 Pb1 116.19(14) 3 . ? Pb21 OS1 Pb1 115.91(14) 4_545 . ? S1 OS1 O 150.20(8) . . ? OS32 OS1 O 124.17(14) 2 . ? OS2 OS1 O 174.50(8) . . ? Pb22 OS1 O 48.75(8) 3 . ? Pb21 OS1 O 49.05(8) 4_545 . ? Pb1 OS1 O 100.34(5) . . ? S1 OS2 OS1 36.89(6) . . ? S1 OS2 OS32 33.50(13) . 2 ? OS1 OS2 OS32 59.76(11) . 2 ? S1 OS2 OS31 33.69(13) . . ? OS1 OS2 OS31 58.97(11) . . ? OS32 OS2 OS31 58.40(8) 2 . ? S1 OS2 Pb21 140.2(3) . . ? OS1 OS2 Pb21 132.3(2) . . ? OS32 OS2 Pb21 156.67(14) 2 . ? OS31 OS2 Pb21 107.6(2) . . ? S1 OS2 Pb22 138.8(3) . 2 ? OS1 OS2 Pb22 131.8(2) . 2 ? OS32 OS2 Pb22 106.6(2) 2 2 ? OS31 OS2 Pb22 157.06(14) . 2 ? Pb21 OS2 Pb22 79.76(4) . 2 ? S1 OS2 Pb1 93.84(8) . . ? OS1 OS2 Pb1 56.96(5) . . ? OS32 OS2 Pb1 108.73(12) 2 . ? OS31 OS2 Pb1 108.17(11) . . ? Pb21 OS2 Pb1 93.05(9) . . ? Pb22 OS2 Pb1 92.77(9) 2 . ? S1 OS2 OS32 98.7(2) . 3 ? OS1 OS2 OS32 73.31(14) . 3 ? OS32 OS2 OS32 130.98(10) 2 3 ? OS31 OS2 OS32 86.61(16) . 3 ? Pb21 OS2 OS32 59.71(10) . 3 ? Pb22 OS2 OS32 115.17(6) 2 3 ? Pb1 OS2 OS32 47.22(7) . 3 ? S1 OS2 Cl1 143.69(9) . . ? OS1 OS2 Cl1 106.81(7) . . ? OS32 OS2 Cl1 145.65(19) 2 . ? OS31 OS2 Cl1 145.70(19) . . ? Pb21 OS2 Cl1 56.48(4) . . ? Pb22 OS2 Cl1 56.45(4) 2 . ? Pb1 OS2 Cl1 49.85(3) . . ? OS32 OS2 Cl1 59.10(6) 3 . ? S1 OS2 Pb1 66.9(2) . 4 ? OS1 OS2 Pb1 82.94(16) . 4 ? OS32 OS2 Pb1 89.99(11) 2 4 ? OS31 OS2 Pb1 33.51(9) . 4 ? Pb21 OS2 Pb1 74.07(12) . 4 ? Pb22 OS2 Pb1 145.26(9) 2 4 ? Pb1 OS2 Pb1 110.85(13) . 4 ? OS32 OS2 Pb1 69.98(11) 3 4 ? Cl1 OS2 Pb1 121.25(13) . 4 ? S1 OS2 Pb1 66.0(2) . 4_545 ? OS1 OS2 Pb1 82.77(16) . 4_545 ? OS32 OS2 Pb1 33.06(10) 2 4_545 ? OS31 OS2 Pb1 90.01(10) . 4_545 ? Pb21 OS2 Pb1 144.96(9) . 4_545 ? Pb22 OS2 Pb1 73.58(11) 2 4_545 ? Pb1 OS2 Pb1 110.32(13) . 4_545 ? OS32 OS2 Pb1 153.89(8) 3 4_545 ? Cl1 OS2 Pb1 120.73(13) . 4_545 ? Pb1 OS2 Pb1 117.93(4) 4 4_545 ? S1 OS2 OS2 69.0(2) . 4_545 ? OS1 OS2 OS2 59.06(19) . 4_545 ? OS32 OS2 OS2 52.79(12) 2 4_545 ? OS31 OS2 OS2 102.68(13) . 4_545 ? Pb21 OS2 OS2 148.36(9) . 4_545 ? Pb22 OS2 OS2 75.88(8) 2 4_545 ? Pb1 OS2 OS2 68.53(11) . 4_545 ? OS32 OS2 OS2 114.07(10) 3 4_545 ? Cl1 OS2 OS2 92.89(9) . 4_545 ? Pb1 OS2 OS2 135.74(6) 4 4_545 ? Pb1 OS2 OS2 41.79(4) 4_545 4_545 ? S1 OS31 OS32 35.27(9) . 2 ? S1 OS31 OS2 33.24(12) . . ? OS32 OS31 OS2 60.17(14) 2 . ? S1 OS31 Pb1 147.61(13) . 4 ? OS32 OS31 Pb1 160.22(15) 2 4 ? OS2 OS31 Pb1 115.33(14) . 4 ? S1 OS31 Pb22 91.03(12) . 3 ? OS32 OS31 Pb22 101.51(11) 2 3 ? OS2 OS31 Pb22 109.46(10) . 3 ? Pb1 OS31 Pb22 98.08(7) 4 3 ? S1 OS32 OS31 36.09(10) 2 2 ? S1 OS32 OS1 36.77(12) 2 2 ? OS31 OS32 OS1 60.00(15) 2 2 ? S1 OS32 OS2 33.82(12) 2 2 ? OS31 OS32 OS2 61.43(15) 2 2 ? OS1 OS32 OS2 59.81(9) 2 2 ? S1 OS32 Pb1 148.97(14) 2 3_445 ? OS31 OS32 Pb1 163.14(16) 2 3_445 ? OS1 OS32 Pb1 135.37(17) 2 3_445 ? OS2 OS32 Pb1 116.80(14) 2 3_445 ? S1 OS32 OH51 140.79(17) 2 3_445 ? OS31 OS32 OH51 112.23(14) 2 3_445 ? OS1 OS32 OH51 169.27(13) 2 3_445 ? OS2 OS32 OH51 124.70(11) 2 3_445 ? Pb1 OS32 OH51 53.53(6) 3_445 3_445 ? S1 OS32 Pb21 89.60(13) 2 3_445 ? OS31 OS32 Pb21 99.67(11) 2 3_445 ? OS1 OS32 Pb21 53.21(10) 2 3_445 ? OS2 OS32 Pb21 109.12(11) 2 3_445 ? Pb1 OS32 Pb21 96.63(8) 3_445 3_445 ? OH51 OS32 Pb21 125.47(8) 3_445 3_445 ? S1 OS32 OS2 103.31(16) 2 3_445 ? OS31 OS32 OS2 136.03(16) 2 3_445 ? OS1 OS32 OS2 76.38(16) 2 3_445 ? OS2 OS32 OS2 93.12(10) 2 3_445 ? Pb1 OS32 OS2 59.06(9) 3_445 3_445 ? OH51 OS32 OS2 111.75(11) 3_445 3_445 ? Pb21 OS32 OS2 52.76(6) 3_445 3_445 ? S1 OS32 Cl1 146.24(14) 2 3_445 ? OS31 OS32 Cl1 132.07(10) 2 3_445 ? OS1 OS32 Cl1 111.37(12) 2 3_445 ? OS2 OS32 Cl1 160.32(15) 2 3_445 ? Pb1 OS32 Cl1 55.21(5) 3_445 3_445 ? OH51 OS32 Cl1 67.48(6) 3_445 3_445 ? Pb21 OS32 Cl1 58.37(4) 3_445 3_445 ? OS2 OS32 Cl1 67.26(7) 3_445 3_445 ? S1 OS32 Cu1 135.90(15) 2 3_445 ? OS31 OS32 Cu1 99.83(11) 2 3_445 ? OS1 OS32 Cu1 139.99(10) 2 3_445 ? OS2 OS32 Cu1 144.15(13) 2 3_445 ? Pb1 OS32 Cu1 71.88(6) 3_445 3_445 ? OH51 OS32 Cu1 30.29(4) 3_445 3_445 ? Pb21 OS32 Cu1 103.85(6) 3_445 3_445 ? OS2 OS32 Cu1 118.39(9) 3_445 3_445 ? Cl1 OS32 Cu1 54.43(4) 3_445 3_445 ? S1 OS32 Pb22 47.86(8) 2 4_455 ? OS31 OS32 Pb22 45.87(8) 2 4_455 ? OS1 OS32 Pb22 31.85(8) 2 4_455 ? OS2 OS32 Pb22 80.81(11) 2 4_455 ? Pb1 OS32 Pb22 150.23(9) 3_445 4_455 ? OH51 OS32 Pb22 137.50(8) 3_445 4_455 ? Pb21 OS32 Pb22 53.80(4) 3_445 4_455 ? OS2 OS32 Pb22 98.32(9) 3_445 4_455 ? Cl1 OS32 Pb22 99.88(6) 3_445 4_455 ? Cu1 OS32 Pb22 108.75(5) 3_445 4_455 ? S1 OS32 Pb22 74.26(9) 2 . ? OS31 OS32 Pb22 100.63(8) 2 . ? OS1 OS32 Pb22 88.81(7) 2 . ? OS2 OS32 Pb22 41.06(12) 2 . ? Pb1 OS32 Pb22 75.74(5) 3_445 . ? OH51 OS32 Pb22 100.32(7) 3_445 . ? Pb21 OS32 Pb22 116.26(8) 3_445 . ? OS2 OS32 Pb22 71.49(5) 3_445 . ? Cl1 OS32 Pb22 127.10(7) 3_445 . ? Cu1 OS32 Pb22 130.54(7) 3_445 . ? Pb22 OS32 Pb22 117.80(6) 4_455 . ? _diffrn_measured_fraction_theta_max 1.000 _diffrn_reflns_theta_full 30.06 _diffrn_measured_fraction_theta_full 1.000 _refine_diff_density_max 2.938 _refine_diff_density_min -1.215 _refine_diff_density_rms 0.205