data_camero
_audit_creation_method SHELXL-97
_chemical_name_systematic
;
?
;
_chemical_name_mineral 'cameronite'
_chemical_compound_source 'Good Hoop mine, Colorado'
_chemical_melting_point ?
_chemical_formula_moiety
'Ag Cu7 Te10'
_chemical_formula_sum
'Ag Cu7 Te10'
_chemical_formula_analytical
'Ag1.06(2) Cu7.08(4) Te9.84(5) Fe0.01(1) S0.01(1)'
_chemical_formula_weight 1828.65
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
'Ag' 'Ag' -0.8971 1.1015
'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
'Cu' 'Cu' 0.3201 1.2651
'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
'Te' 'Te' -0.5308 1.6751
'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_symmetry_cell_setting monoclinic
_space_group_IT_number '15'
_space_group_name_H-M_alt 'C 2/c'
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
_cell_length_a 17.9060(10)
_cell_length_b 17.9270(10)
_cell_length_c 21.230(2)
_cell_angle_alpha 90.00
_cell_angle_beta 98.081(8)
_cell_angle_gamma 90.00
_cell_volume 6747.2(8)
_cell_formula_units_Z 14
_cell_measurement_temperature 293(2)
_cell_measurement_reflns_used 532
_cell_measurement_theta_min 9.84
_cell_measurement_theta_max 19.98
_exptl_crystal_description block
_exptl_crystal_colour black
_exptl_crystal_size_max 0.115
_exptl_crystal_size_mid 0.085
_exptl_crystal_size_min 0.065
_exptl_crystal_density_meas ?
_exptl_crystal_density_diffrn 6.301
_exptl_crystal_density_method 'not measured'
_exptl_crystal_F_000 10780.6
_exptl_absorpt_coefficient_mu 23.368
_exptl_absorpt_correction_type 'gaussian'
_exptl_absorpt_correction_T_min 0.106
_exptl_absorpt_correction_T_max 0.219
_exptl_absorpt_process_details 'ABSPACK (Oxford Diffraction, 2006)'
_exptl_special_details
;
?
;
_diffrn_ambient_temperature 293(2)
_diffrn_radiation_wavelength 0.71073
_diffrn_radiation_type MoK\a
_diffrn_radiation_source 'fine-focus sealed tube'
_diffrn_radiation_monochromator graphite
_diffrn_measurement_device_type 'Oxford Xcalibur 3'
_diffrn_measurement_method '\w scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number 41
_diffrn_standards_interval_count 185
_diffrn_standards_interval_time ?
_diffrn_standards_decay_% 0
_diffrn_reflns_number 78245
_diffrn_reflns_av_R_equivalents 0.0366
_diffrn_reflns_av_sigmaI/netI 0.0582
_diffrn_reflns_limit_h_min -25
_diffrn_reflns_limit_h_max 25
_diffrn_reflns_limit_k_min -25
_diffrn_reflns_limit_k_max 25
_diffrn_reflns_limit_l_min -29
_diffrn_reflns_limit_l_max 29
_diffrn_reflns_theta_min 5.80
_diffrn_reflns_theta_max 30.00
_reflns_number_total 9688
_reflns_number_gt 3839
_reflns_threshold_expression >2sigma(I)
_computing_data_collection 'CrysAlis (Oxford Diffraction 2006)'
_computing_cell_refinement 'CrysAlis (Oxford Diffraction 2006)'
_computing_data_reduction 'CrysAlis (Oxford Diffraction 2006)'
_computing_structure_solution 'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_refinement 'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics 'Diamond (Brandenburg, 2001)'
_computing_publication_material 'SHELXL-97 (Sheldrick, 2008)'
_refine_special_details
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type full
_refine_ls_weighting_scheme calc
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.1090P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary direct
_atom_sites_solution_secondary difmap
_atom_sites_solution_hydrogens none
_refine_ls_hydrogen_treatment undef
_refine_ls_extinction_method none
_refine_ls_extinction_coef none
_refine_ls_number_reflns 9688
_refine_ls_number_parameters 292
_refine_ls_number_restraints 0
_refine_ls_R_factor_all 0.0216
_refine_ls_R_factor_gt 0.0210
_refine_ls_wR_factor_ref 0.0490
_refine_ls_wR_factor_gt 0.0488
_refine_ls_goodness_of_fit_ref 0.870
_refine_ls_restrained_S_all 0.870
_refine_ls_shift/su_max 0.006
_refine_ls_shift/su_mean 0.001
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Te1 Te 0.5000 0.041272(5) 0.2500 0.01766(3) Uani 1 2 d S . .
Te2 Te 0.0000 0.210338(6) 0.2500 0.02099(3) Uani 1 2 d S . .
Te3 Te 0.0000 0.123149(6) 0.7500 0.02071(3) Uani 1 2 d S . .
Te4 Te 0.835113(4) 0.376439(4) 0.251411(3) 0.02200(3) Uani 1 1 d . . .
Te5 Te 0.358290(4) 0.288967(4) -0.108482(3) 0.02135(3) Uani 1 1 d . . .
Te6 Te 0.666249(5) 0.206467(4) 0.251036(4) 0.02069(3) Uani 1 1 d . . .
Te7 Te 0.311121(4) 0.041591(3) 0.109886(4) 0.02157(3) Uani 1 1 d . . .
Te8 Te 0.478428(5) -0.122799(4) 0.110142(4) 0.02300(3) Uani 1 1 d . . .
Te9 Te 0.194542(6) 0.123686(5) -0.108793(4) 0.02388(3) Uani 1 1 d . . .
Te10 Te 0.641929(6) 0.039075(5) 0.111922(6) 0.02365(3) Uani 1 1 d . . .
Te11 Te 0.476675(6) 0.204339(6) 0.110747(5) 0.02075(3) Uani 1 1 d . . .
Te12 Te 0.831844(6) -0.041590(5) 0.747907(5) 0.02551(3) Uani 1 1 d . . .
Te13 Te 0.025378(7) -0.041174(5) -0.107167(6) 0.02215(4) Uani 1 1 d . . .
Te14 Te 0.646378(6) 0.376196(5) 0.106946(5) 0.02412(3) Uani 1 1 d . . .
Te15 Te 0.809574(5) 0.208891(4) 0.111224(4) 0.01983(3) Uani 1 1 d . . .
Te16 Te 0.452296(7) 0.376501(5) -0.036558(5) 0.02051(3) Uani 1 1 d . . .
Te17 Te 0.546182(7) 0.293549(5) 0.036913(6) 0.02190(4) Uani 1 1 d . . .
Te18 Te 0.378792(8) 0.126708(6) 0.029071(7) 0.02185(3) Uani 1 1 d . . .
Te19 Te 0.284180(6) 0.210017(4) -0.032196(5) 0.02119(3) Uani 1 1 d . . .
Ag1 Ag 0.115992(9) 0.045060(7) -0.036220(7) 0.01961(5) Uani 0.7008(7) 1 d P . .
Ag2 Ag 0.209464(9) -0.042355(6) 0.030806(7) 0.01957(5) Uani 0.7369(7) 1 d P . .
Ag3 Ag 0.733704(8) 0.291402(6) 0.175078(7) 0.01447(5) Uani 0.6483(7) 1 d P . .
Ag4 Ag 0.548143(10) -0.041555(7) 0.028293(9) 0.02767(5) Uani 0.7818(7) 1 d P . .
Ag5 Ag -0.093670(9) 0.879470(9) 0.675700(8) 0.02702(6) Uani 0.7326(8) 1 d P . .
Ag6 Ag -0.070723(8) 0.043392(7) 0.822239(6) 0.02390(5) Uani 0.7728(8) 1 d P . .
Cu7 Cu 0.382914(11) 0.788241(9) 0.032437(9) 0.02171(4) Uani 1 1 d . . .
Cu8 Cu 0.573341(9) 0.126046(8) 0.176352(8) 0.02044(5) Uani 1 1 d . . .
Cu9 Cu 0.761769(11) 0.457468(9) 0.323851(9) 0.02501(5) Uani 1 1 d . . .
Cu10 Cu 0.405673(11) -0.042242(9) 0.176939(9) 0.02447(5) Uani 1 1 d . . .
Cu11 Cu 0.931147(10) 0.291467(8) 0.323874(8) 0.02066(5) Uani 1 1 d . . .
Cu12 Cu 0.590961(10) 0.293941(8) 0.320657(7) 0.02025(5) Uani 1 1 d . . .
Cu13 Cu 0.261802(10) 0.374311(9) 0.822078(8) 0.02389(5) Uani 1 1 d . . .
Cu14 Cu 0.714663(11) 0.124980(9) 0.035825(9) 0.02241(5) Uani 1 1 d . . .
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Te1 0.02055(6) 0.02102(5) 0.02038(6) 0.000 0.00291(4) 0.000
Te2 0.02136(6) 0.02095(6) 0.02067(6) 0.000 0.00301(4) 0.000
Te3 0.02102(6) 0.02069(5) 0.02043(6) 0.000 0.00294(4) 0.000
Te4 0.02266(5) 0.02238(4) 0.02104(4) 0.00003(2) 0.00217(3) 0.00002(2)
Te5 0.02255(4) 0.02036(4) 0.02208(4) -0.00002(2) 0.00251(3) 0.00003(2)
Te6 0.02100(5) 0.02072(5) 0.02036(5) -0.00002(2) 0.00237(3) 0.00005(2)
Te7 0.02091(5) 0.02259(4) 0.02122(4) 0.00001(2) 0.00208(3) 0.00001(2)
Te8 0.02329(5) 0.02203(4) 0.02268(4) -0.00002(2) 0.00220(3) -0.00002(2)
Te9 0.02213(5) 0.02187(5) 0.02064(5) 0.00000(2) 0.00218(4) 0.00001(2)
Te10 0.02291(6) 0.02267(5) 0.02236(6) -0.00003(3) 0.00215(4) -0.00003(3)
Te11 0.02104(6) 0.02074(5) 0.02045(6) -0.00001(3) 0.00227(4) -0.00006(3)
Te12 0.02177(6) 0.02250(5) 0.02224(5) 0.00004(3) 0.00256(4) -0.00001(3)
Te13 0.02240(7) 0.02215(6) 0.02190(6) -0.00004(3) 0.00256(5) 0.00004(3)
Te14 0.02456(5) 0.02406(5) 0.02374(5) -0.00004(2) 0.00243(4) 0.00000(2)
Te15 0.02010(5) 0.01986(5) 0.01954(5) 0.00001(2) 0.00283(3) 0.00004(2)
Te16 0.02076(6) 0.02152(5) 0.02028(5) 0.00002(3) 0.00210(4) -0.00002(3)
Te17 0.02223(6) 0.02187(5) 0.02160(6) -0.00001(3) 0.00227(4) 0.00003(3)
Te18 0.02209(6) 0.02215(6) 0.02203(6) 0.00001(3) 0.00234(4) -0.00004(3)
Te19 0.02143(5) 0.02122(5) 0.02094(5) 0.00001(2) 0.00202(3) -0.00004(2)
Ag1 0.01992(8) 0.01966(7) 0.01927(8) -0.00002(4) 0.00285(5) 0.00002(4)
Ag2 0.01992(8) 0.01955(7) 0.01927(7) 0.00002(3) 0.00281(5) 0.00001(3)
Ag3 0.01476(8) 0.01450(7) 0.01420(7) 0.00003(3) 0.00217(4) -0.00003(3)
Ag4 0.02794(9) 0.02769(8) 0.02735(8) -0.00002(4) 0.00380(5) 0.00001(4)
Ag5 0.02732(9) 0.02698(8) 0.02676(8) -0.00003(4) 0.00383(6) -0.00001(4)
Ag6 0.02407(9) 0.02397(8) 0.02364(8) -0.00003(4) 0.00329(5) 0.00005(4)
Cu7 0.02196(9) 0.02168(8) 0.02149(8) 0.00013(5) 0.00310(6) 0.00001(5)
Cu8 0.02082(9) 0.02035(8) 0.02023(8) 0.00000(4) 0.00320(6) -0.00002(4)
Cu9 0.02534(10) 0.02501(9) 0.02472(9) 0.00009(5) 0.00364(7) -0.00011(5)
Cu10 0.02467(10) 0.02458(9) 0.02422(9) -0.00002(5) 0.00364(7) -0.00005(5)
Cu11 0.02105(9) 0.02067(8) 0.02028(8) -0.00002(4) 0.00300(6) -0.00002(4)
Cu12 0.02046(9) 0.02019(8) 0.02011(8) -0.00002(4) 0.00294(6) -0.00004(4)
Cu13 0.02408(10) 0.02392(9) 0.02366(9) 0.00004(5) 0.00336(7) -0.00008(5)
Cu14 0.02272(9) 0.02240(8) 0.02210(8) 0.00001(5) 0.00312(7) -0.00002(5)
_geom_special_details
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Te1 Cu10 2.6007(3) . ?
Te1 Cu10 2.6007(3) 2_655 ?
Te1 Cu8 2.6564(2) 2_655 ?
Te1 Cu8 2.6564(2) . ?
Te2 Cu11 2.5766(2) 1_455 ?
Te2 Cu11 2.5766(2) 2_655 ?
Te2 Ag5 2.6739(3) 6_565 ?
Te2 Ag5 2.6739(3) 5_566 ?
Te3 Cu12 2.5348(2) 8_456 ?
Te3 Cu12 2.5348(2) 7_556 ?
Te3 Ag6 2.5585(2) 2_556 ?
Te3 Ag6 2.5585(2) . ?
Te4 Cu9 2.6015(2) . ?
Te4 Cu10 2.6044(2) 3 ?
Te4 Cu11 2.6268(3) . ?
Te4 Ag3 2.7240(2) . ?
Te5 Cu11 2.5239(2) 8_455 ?
Te5 Cu13 2.6044(3) 1_554 ?
Te5 Te16 2.6277(2) . ?
Te5 Te19 2.6441(2) . ?
Te6 Cu13 2.5639(3) 8 ?
Te6 Cu8 2.5726(3) . ?
Te6 Ag3 2.6316(2) . ?
Te6 Cu12 2.6498(2) . ?
Te7 Cu10 2.5444(3) . ?
Te7 Cu13 2.5680(2) 7_556 ?
Te7 Te18 2.7064(2) . ?
Te7 Ag2 2.7454(3) . ?
Te8 Cu11 2.5117(3) 4_645 ?
Te8 Cu10 2.5126(3) . ?
Te8 Ag4 2.7035(3) . ?
Te8 Cu7 2.7197(3) 1_545 ?
Te9 Cu9 2.4687(3) 8_455 ?
Te9 Te19 2.6234(2) . ?
Te9 Ag1 2.6359(2) . ?
Te9 Cu12 2.6614(3) 8_455 ?
Te10 Cu8 2.5065(3) . ?
Te10 Cu9 2.5124(3) 4_645 ?
Te10 Ag4 2.6876(3) . ?
Te10 Cu14 2.6962(3) . ?
Te11 Cu8 2.4956(3) . ?
Te11 Cu12 2.5814(2) 2_655 ?
Te11 Te17 2.6669(2) . ?
Te11 Te18 2.6760(3) . ?
Te12 Cu9 2.5859(3) 7_656 ?
Te12 Ag5 2.5897(3) 1_645 ?
Te12 Cu13 2.6231(2) 3_545 ?
Te12 Ag6 2.6610(2) 1_655 ?
Te13 Ag5 2.4771(3) 2_545 ?
Te13 Ag1 2.5698(3) . ?
Te13 Te16 2.5863(2) 3_445 ?
Te13 Ag6 2.6039(3) 1_554 ?
Te14 Ag3 2.4924(2) . ?
Te14 Ag2 2.5562(2) 3 ?
Te14 Ag6 2.5973(2) 7_556 ?
Te14 Te17 2.6220(2) . ?
Te15 Ag3 2.5277(2) . ?
Te15 Ag5 2.5919(2) 6_665 ?
Te15 Cu14 2.6360(3) . ?
Te15 Cu7 2.6764(3) 3_545 ?
Te16 Ag1 2.5280(3) 7 ?
Te16 Te13 2.5863(2) 3 ?
Te16 Te17 2.5948(2) . ?
Te17 Cu7 2.5407(3) 5_665 ?
Te18 Ag4 2.4440(3) 5_655 ?
Te18 Te19 2.4845(2) . ?
Te19 Te19 2.4275(2) 7 ?
Ag1 Te16 2.5280(3) 7 ?
Ag1 Ag2 2.5714(3) . ?
Ag2 Te14 2.5562(2) 3_445 ?
Ag2 Cu14 2.5654(3) 5_655 ?
Ag4 Te18 2.4440(3) 5_655 ?
Ag4 Ag4 2.4603(4) 5_655 ?
Ag5 Te13 2.4771(3) 2_565 ?
Ag5 Te12 2.5897(2) 1_465 ?
Ag5 Te15 2.5919(2) 6_466 ?
Ag5 Te2 2.6739(3) 5_566 ?
Ag6 Te14 2.5973(2) 7_556 ?
Ag6 Te13 2.6039(3) 1_556 ?
Ag6 Te12 2.6610(2) 1_455 ?
Cu7 Te17 2.5407(3) 5_665 ?
Cu7 Cu14 2.6194(3) 5_665 ?
Cu7 Te15 2.6764(3) 3_455 ?
Cu7 Te8 2.7197(3) 1_565 ?
Cu9 Te9 2.4687(3) 8_556 ?
Cu9 Te10 2.5124(3) 4_655 ?
Cu9 Te12 2.5859(3) 7_656 ?
Cu10 Te4 2.6044(2) 3_445 ?
Cu11 Te8 2.5117(2) 4_655 ?
Cu11 Te5 2.5239(2) 8_556 ?
Cu11 Te2 2.5766(2) 1_655 ?
Cu12 Te3 2.5348(2) 7_556 ?
Cu12 Te11 2.5814(2) 2_655 ?
Cu12 Te9 2.6614(3) 8_556 ?
Cu13 Te6 2.5639(3) 8_456 ?
Cu13 Te7 2.5680(2) 7_556 ?
Cu13 Te5 2.6044(3) 1_556 ?
Cu13 Te12 2.6231(3) 3_455 ?
Cu14 Ag2 2.5654(3) 5_655 ?
Cu14 Cu7 2.6194(3) 5_665 ?
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cu10 Te1 Cu10 109.706(10) . 2_655 ?
Cu10 Te1 Cu8 110.307(7) . 2_655 ?
Cu10 Te1 Cu8 108.160(8) 2_655 2_655 ?
Cu10 Te1 Cu8 108.160(8) . . ?
Cu10 Te1 Cu8 110.307(7) 2_655 . ?
Cu8 Te1 Cu8 110.204(9) 2_655 . ?
Cu11 Te2 Cu11 111.268(10) 1_455 2_655 ?
Cu11 Te2 Ag5 112.633(7) 1_455 6_565 ?
Cu11 Te2 Ag5 107.154(8) 2_655 6_565 ?
Cu11 Te2 Ag5 107.154(8) 1_455 5_566 ?
Cu11 Te2 Ag5 112.633(7) 2_655 5_566 ?
Ag5 Te2 Ag5 105.956(10) 6_565 5_566 ?
Cu12 Te3 Cu12 108.201(10) 8_456 7_556 ?
Cu12 Te3 Ag6 110.573(6) 8_456 2_556 ?
Cu12 Te3 Ag6 107.696(8) 7_556 2_556 ?
Cu12 Te3 Ag6 107.696(7) 8_456 . ?
Cu12 Te3 Ag6 110.573(6) 7_556 . ?
Ag6 Te3 Ag6 112.049(9) 2_556 . ?
Cu9 Te4 Cu10 112.001(8) . 3 ?
Cu9 Te4 Cu11 108.717(9) . . ?
Cu10 Te4 Cu11 110.281(7) 3 . ?
Cu9 Te4 Ag3 108.330(7) . . ?
Cu10 Te4 Ag3 106.967(8) 3 . ?
Cu11 Te4 Ag3 110.526(8) . . ?
Cu11 Te5 Cu13 111.615(8) 8_455 1_554 ?
Cu11 Te5 Te16 109.371(7) 8_455 . ?
Cu13 Te5 Te16 107.332(8) 1_554 . ?
Cu11 Te5 Te19 112.753(7) 8_455 . ?
Cu13 Te5 Te19 108.122(7) 1_554 . ?
Te16 Te5 Te19 107.421(7) . . ?
Cu13 Te6 Cu8 111.486(8) 8 . ?
Cu13 Te6 Ag3 111.188(7) 8 . ?
Cu8 Te6 Ag3 105.030(8) . . ?
Cu13 Te6 Cu12 110.848(8) 8 . ?
Cu8 Te6 Cu12 109.865(7) . . ?
Ag3 Te6 Cu12 108.224(8) . . ?
Cu10 Te7 Cu13 112.523(9) . 7_556 ?
Cu10 Te7 Te18 111.451(8) . . ?
Cu13 Te7 Te18 109.507(7) 7_556 . ?
Cu10 Te7 Ag2 110.499(8) . . ?
Cu13 Te7 Ag2 108.658(8) 7_556 . ?
Te18 Te7 Ag2 103.817(8) . . ?
Cu11 Te8 Cu10 112.437(9) 4_645 . ?
Cu11 Te8 Ag4 111.619(8) 4_645 . ?
Cu10 Te8 Ag4 112.087(8) . . ?
Cu11 Te8 Cu7 106.296(9) 4_645 1_545 ?
Cu10 Te8 Cu7 110.344(8) . 1_545 ?
Ag4 Te8 Cu7 103.524(9) . 1_545 ?
Cu9 Te9 Te19 113.644(8) 8_455 . ?
Cu9 Te9 Ag1 111.540(8) 8_455 . ?
Te19 Te9 Ag1 106.463(8) . . ?
Cu9 Te9 Cu12 111.039(9) 8_455 8_455 ?
Te19 Te9 Cu12 109.802(8) . 8_455 ?
Ag1 Te9 Cu12 103.813(9) . 8_455 ?
Cu8 Te10 Cu9 114.684(10) . 4_645 ?
Cu8 Te10 Ag4 112.734(9) . . ?
Cu9 Te10 Ag4 111.272(8) 4_645 . ?
Cu8 Te10 Cu14 106.661(8) . . ?
Cu9 Te10 Cu14 107.776(9) 4_645 . ?
Ag4 Te10 Cu14 102.766(10) . . ?
Cu8 Te11 Cu12 112.254(9) . 2_655 ?
Cu8 Te11 Te17 108.718(8) . . ?
Cu12 Te11 Te17 104.664(9) 2_655 . ?
Cu8 Te11 Te18 114.133(9) . . ?
Cu12 Te11 Te18 111.881(8) 2_655 . ?
Te17 Te11 Te18 104.376(9) . . ?
Cu9 Te12 Ag5 108.366(9) 7_656 1_645 ?
Cu9 Te12 Cu13 111.334(8) 7_656 3_545 ?
Ag5 Te12 Cu13 111.763(8) 1_645 3_545 ?
Cu9 Te12 Ag6 109.399(8) 7_656 1_655 ?
Ag5 Te12 Ag6 108.337(7) 1_645 1_655 ?
Cu13 Te12 Ag6 107.578(8) 3_545 1_655 ?
Ag5 Te13 Ag1 111.506(9) 2_545 . ?
Ag5 Te13 Te16 110.150(8) 2_545 3_445 ?
Ag1 Te13 Te16 109.437(9) . 3_445 ?
Ag5 Te13 Ag6 109.703(9) 2_545 1_554 ?
Ag1 Te13 Ag6 107.387(8) . 1_554 ?
Te16 Te13 Ag6 108.575(8) 3_445 1_554 ?
Ag3 Te14 Ag2 114.734(8) . 3 ?
Ag3 Te14 Ag6 109.773(8) . 7_556 ?
Ag2 Te14 Ag6 111.211(7) 3 7_556 ?
Ag3 Te14 Te17 107.933(8) . . ?
Ag2 Te14 Te17 106.988(8) 3 . ?
Ag6 Te14 Te17 105.716(8) 7_556 . ?
Ag3 Te15 Ag5 116.370(9) . 6_665 ?
Ag3 Te15 Cu14 108.083(8) . . ?
Ag5 Te15 Cu14 107.335(8) 6_665 . ?
Ag3 Te15 Cu7 111.843(8) . 3_545 ?
Ag5 Te15 Cu7 107.734(8) 6_665 3_545 ?
Cu14 Te15 Cu7 104.767(9) . 3_545 ?
Ag1 Te16 Te13 111.373(7) 7 3 ?
Ag1 Te16 Te17 106.233(9) 7 . ?
Te13 Te16 Te17 109.730(8) 3 . ?
Ag1 Te16 Te5 111.221(8) 7 . ?
Te13 Te16 Te5 109.813(8) 3 . ?
Te17 Te16 Te5 108.363(7) . . ?
Cu7 Te17 Te16 108.463(9) 5_665 . ?
Cu7 Te17 Te14 107.270(9) 5_665 . ?
Te16 Te17 Te14 110.541(7) . . ?
Cu7 Te17 Te11 107.881(8) 5_665 . ?
Te16 Te17 Te11 112.367(8) . . ?
Te14 Te17 Te11 110.135(8) . . ?
Ag4 Te18 Te19 119.208(11) 5_655 . ?
Ag4 Te18 Te11 107.457(9) 5_655 . ?
Te19 Te18 Te11 111.279(8) . . ?
Ag4 Te18 Te7 106.407(8) 5_655 . ?
Te19 Te18 Te7 109.737(8) . . ?
Te11 Te18 Te7 101.143(9) . . ?
Te19 Te19 Te18 114.889(9) 7 . ?
Te19 Te19 Te9 112.610(8) 7 . ?
Te18 Te19 Te9 106.418(8) . . ?
Te19 Te19 Te5 111.411(7) 7 . ?
Te18 Te19 Te5 106.167(7) . . ?
Te9 Te19 Te5 104.603(8) . . ?
Te16 Ag1 Te13 111.904(9) 7 . ?
Te16 Ag1 Ag2 109.505(10) 7 . ?
Te13 Ag1 Ag2 105.423(9) . . ?
Te16 Ag1 Te9 113.796(8) 7 . ?
Te13 Ag1 Te9 108.899(9) . . ?
Ag2 Ag1 Te9 106.861(9) . . ?
Te14 Ag2 Cu14 109.526(8) 3_445 5_655 ?
Te14 Ag2 Ag1 112.763(9) 3_445 . ?
Cu14 Ag2 Ag1 113.621(11) 5_655 . ?
Te14 Ag2 Te7 103.907(9) 3_445 . ?
Cu14 Ag2 Te7 107.259(9) 5_655 . ?
Ag1 Ag2 Te7 109.170(8) . . ?
Te14 Ag3 Te15 112.725(9) . . ?
Te14 Ag3 Te6 113.826(8) . . ?
Te15 Ag3 Te6 108.520(7) . . ?
Te14 Ag3 Te4 108.378(8) . . ?
Te15 Ag3 Te4 106.438(7) . . ?
Te6 Ag3 Te4 106.514(8) . . ?
Te18 Ag4 Ag4 121.494(15) 5_655 5_655 ?
Te18 Ag4 Te10 109.667(10) 5_655 . ?
Ag4 Ag4 Te10 109.072(10) 5_655 . ?
Te18 Ag4 Te8 108.160(8) 5_655 . ?
Ag4 Ag4 Te8 106.552(11) 5_655 . ?
Te10 Ag4 Te8 99.627(11) . . ?
Te13 Ag5 Te12 111.820(9) 2_565 1_465 ?
Te13 Ag5 Te15 112.911(10) 2_565 6_466 ?
Te12 Ag5 Te15 106.556(8) 1_465 6_466 ?
Te13 Ag5 Te2 111.826(8) 2_565 5_566 ?
Te12 Ag5 Te2 108.203(8) 1_465 5_566 ?
Te15 Ag5 Te2 105.121(9) 6_466 5_566 ?
Te3 Ag6 Te14 112.282(8) . 7_556 ?
Te3 Ag6 Te13 109.125(7) . 1_556 ?
Te14 Ag6 Te13 110.256(8) 7_556 1_556 ?
Te3 Ag6 Te12 107.636(8) . 1_455 ?
Te14 Ag6 Te12 108.011(7) 7_556 1_455 ?
Te13 Ag6 Te12 109.459(8) 1_556 1_455 ?
Te17 Cu7 Cu14 111.774(11) 5_665 5_665 ?
Te17 Cu7 Te15 112.612(9) 5_665 3_455 ?
Cu14 Cu7 Te15 108.282(10) 5_665 3_455 ?
Te17 Cu7 Te8 111.534(10) 5_665 1_565 ?
Cu14 Cu7 Te8 107.518(9) 5_665 1_565 ?
Te15 Cu7 Te8 104.746(10) 3_455 1_565 ?
Te11 Cu8 Te10 113.571(10) . . ?
Te11 Cu8 Te6 111.498(9) . . ?
Te10 Cu8 Te6 111.156(8) . . ?
Te11 Cu8 Te1 106.784(8) . . ?
Te10 Cu8 Te1 106.621(8) . . ?
Te6 Cu8 Te1 106.751(8) . . ?
Te9 Cu9 Te10 112.468(11) 8_556 4_655 ?
Te9 Cu9 Te12 110.882(9) 8_556 7_656 ?
Te10 Cu9 Te12 108.588(9) 4_655 7_656 ?
Te9 Cu9 Te4 109.947(9) 8_556 . ?
Te10 Cu9 Te4 106.319(9) 4_655 . ?
Te12 Cu9 Te4 108.461(9) 7_656 . ?
Te8 Cu10 Te7 112.379(9) . . ?
Te8 Cu10 Te1 108.826(9) . . ?
Te7 Cu10 Te1 108.599(9) . . ?
Te8 Cu10 Te4 110.804(8) . 3_445 ?
Te7 Cu10 Te4 109.198(8) . 3_445 ?
Te1 Cu10 Te4 106.857(9) . 3_445 ?
Te8 Cu11 Te5 112.117(9) 4_655 8_556 ?
Te8 Cu11 Te2 111.026(8) 4_655 1_655 ?
Te5 Cu11 Te2 110.712(8) 8_556 1_655 ?
Te8 Cu11 Te4 106.821(8) 4_655 . ?
Te5 Cu11 Te4 108.443(8) 8_556 . ?
Te2 Cu11 Te4 107.500(9) 1_655 . ?
Te3 Cu12 Te11 112.664(8) 7_556 2_655 ?
Te3 Cu12 Te6 110.602(8) 7_556 . ?
Te11 Cu12 Te6 105.204(9) 2_655 . ?
Te3 Cu12 Te9 110.284(8) 7_556 8_556 ?
Te11 Cu12 Te9 111.894(8) 2_655 8_556 ?
Te6 Cu12 Te9 105.863(8) . 8_556 ?
Te6 Cu13 Te7 108.205(8) 8_456 7_556 ?
Te6 Cu13 Te5 109.628(9) 8_456 1_556 ?
Te7 Cu13 Te5 112.074(9) 7_556 1_556 ?
Te6 Cu13 Te12 107.899(9) 8_456 3_455 ?
Te7 Cu13 Te12 108.908(8) 7_556 3_455 ?
Te5 Cu13 Te12 110.019(8) 1_556 3_455 ?
Ag2 Cu14 Cu7 113.679(12) 5_655 5_665 ?
Ag2 Cu14 Te15 108.551(9) 5_655 . ?
Cu7 Cu14 Te15 108.663(9) 5_665 . ?
Ag2 Cu14 Te10 109.784(8) 5_655 . ?
Cu7 Cu14 Te10 109.264(10) 5_665 . ?
Te15 Cu14 Te10 106.654(10) . . ?
_diffrn_measured_fraction_theta_max 0.984
_diffrn_reflns_theta_full 30.00
_diffrn_measured_fraction_theta_full 0.984
_refine_diff_density_max 1.468
_refine_diff_density_min -2.011
_refine_diff_density_rms 0.230