data_cuproneyite _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'Ag Bi51 Cu14 Pb52 S136' _chemical_formula_weight 26789.45 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source 'S' 'S' 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Cu' 'Cu' 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Ag' 'Ag' -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Pb' 'Pb' -3.3944 10.1111 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Bi' 'Bi' -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting 'Monoclinic' _symmetry_space_group_name_H-M 'C2/m ' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z' '-x, -y, -z' 'x, -y, z' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z' _cell_length_a 37.432(8) _cell_length_b 4.0529(9) _cell_length_c 43.545(9) _cell_angle_alpha 90.00 _cell_angle_beta 108.80 _cell_angle_gamma 90.00 _cell_volume 6254(2) _cell_formula_units_Z 1 _cell_measurement_temperature 546(2) _cell_measurement_reflns_used ? _cell_measurement_theta_min ? _cell_measurement_theta_max ? _exptl_crystal_description ? _exptl_crystal_colour ? _exptl_crystal_size_min 0.04 _exptl_crystal_size_mid 0.08 _exptl_crystal_size_max 0.15 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 7.113 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 11126 _exptl_absorpt_coefficient_mu 72.953 _exptl_absorpt_correction_type 'empirical' _exptl_absorpt_correction_T_min 0.0999 _exptl_absorpt_correction_T_max 0.7488 _exptl_absorpt_process_details ? _exptl_special_details ; ? ; _diffrn_ambient_temperature 546(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type ? _diffrn_measurement_method ? _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 21473 _diffrn_reflns_av_R_equivalents 0.1124 _diffrn_reflns_av_sigmaI/netI 0.1040 _diffrn_reflns_limit_h_min -50 _diffrn_reflns_limit_h_max 39 _diffrn_reflns_limit_k_min -5 _diffrn_reflns_limit_k_max 5 _diffrn_reflns_limit_l_min -57 _diffrn_reflns_limit_l_max 56 _diffrn_reflns_theta_min 1.39 _diffrn_reflns_theta_max 28.36 _reflns_number_total 8278 _reflns_number_gt 6050 _reflns_threshold_expression >2sigma(I) _computing_data_collection ? _computing_cell_refinement ? _computing_data_reduction ? _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics ? _computing_publication_material ? _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0916P)^2^+361.7288P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment mixed _refine_ls_extinction_method SHELXL _refine_ls_extinction_coef 0.000006(3) _refine_ls_extinction_expression 'Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^' _refine_ls_number_reflns 8278 _refine_ls_number_parameters 385 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.1075 _refine_ls_R_factor_gt 0.0808 _refine_ls_wR_factor_ref 0.1957 _refine_ls_wR_factor_gt 0.1817 _refine_ls_goodness_of_fit_ref 1.062 _refine_ls_restrained_S_all 1.062 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Bi1 Bi 0.09479(4) 0.0000 0.94994(3) 0.0155(3) Uani 1 2 d S . . Bi2 Bi 0.43264(4) 0.0000 0.13679(3) 0.0167(3) Uani 1 2 d S . . Pb3 Pb 0.31779(4) 0.0000 0.07426(3) 0.0176(3) Uani 1 2 d S . . Pb4 Pb 0.20486(4) 0.0000 0.01401(3) 0.0172(3) Uani 1 2 d S . . Pb5 Pb 0.04094(4) 0.0000 0.77609(3) 0.0173(3) Uani 1 2 d S . . Pb6 Pb 0.15607(4) 0.0000 0.83874(3) 0.0167(3) Uani 1 2 d S . . Pb7 Pb 0.27069(4) 0.0000 0.90086(4) 0.0184(3) Uani 1 2 d S . . Bi8 Bi 0.48443(4) 0.0000 0.30993(3) 0.0146(3) Uani 1 2 d S . . Pb9 Pb 0.37119(4) 0.0000 0.24780(3) 0.0167(3) Uani 1 2 d S . . Bi10 Bi 0.25622(4) 0.0000 0.18681(4) 0.0184(3) Uani 1 2 d S . . Bi11 Bi 0.09895(4) 0.0000 0.66333(4) 0.0187(3) Uani 1 2 d S . . Bi12 Bi 0.21207(4) 0.0000 0.72516(3) 0.0157(3) Uani 1 2 d S . . Bi13 Bi 0.40254(4) 0.0000 0.52779(3) 0.0156(3) Uani 1 2 d S . . Pb14 Pb 0.29539(5) 0.0000 0.54228(4) 0.0215(3) Uani 1 2 d S . . Bi15 Bi 0.18339(4) 0.0000 0.53685(3) 0.0154(3) Uani 1 2 d S . . Bi16 Bi 0.08132(6) 0.0000 0.55147(5) 0.0183(7) Uani 0.764(16) 2 d SP . . Ag Ag 0.08132(6) 0.0000 0.55147(5) 0.0183(7) Uani 0.236(16) 2 d SP . . Bi17 Bi 0.37479(4) 0.0000 0.85603(4) 0.0193(3) Uani 1 2 d S . . Pb18 Pb 0.33283(5) 0.0000 0.75041(4) 0.0231(3) Uani 1 2 d S . . Bi19 Bi 0.31854(4) 0.0000 0.65074(4) 0.0179(3) Uani 1 2 d S . . Bi20 Bi 0.02900(5) 0.0000 0.08667(4) 0.0249(4) Uani 1 2 d S . . Bi21 Bi 0.06829(5) 0.0000 0.19275(4) 0.0205(3) Uani 1 2 d S . . Pb22 Pb 0.07810(5) 0.0000 0.28961(4) 0.0277(4) Uani 1 2 d S . . Pb23 Pb 0.10223(5) 0.0000 0.38832(4) 0.0223(3) Uani 1 2 d S . . Pb24 Pb 0.38853(6) 0.0000 0.95691(5) 0.0371(5) Uani 1 2 d S . . Pb25 Pb 0.00258(5) 0.0000 0.41319(5) 0.0349(5) Uani 1 2 d S . . Pb26 Pb 0.31892(6) 0.0000 0.37196(5) 0.0337(4) Uani 1 2 d S . . Cu Cu 0.5000 0.0000 0.5000 0.041(2) Uani 1 4 d S . . Cu1 Cu 0.46890(16) 0.0000 0.01044(14) 0.0306(12) Uani 1 2 d S . . Cu2 Cu 0.23127(16) 0.0000 0.30923(15) 0.0306(13) Uani 1 2 d S . . Cu3 Cu 0.74933(15) 0.0000 0.58969(15) 0.0287(12) Uani 1 2 d S . . S1 S 0.0649(3) 0.0000 -0.0044(2) 0.0140(18) Uani 1 2 d S . . S2 S 0.4541(2) 0.0000 0.0831(2) 0.0136(18) Uani 1 2 d S . . S3 S 0.3520(3) 0.0000 0.0180(3) 0.026(2) Uani 1 2 d S . . S4 S 0.0203(3) 0.0000 0.8342(2) 0.0167(19) Uani 1 2 d S . . S5 S 0.1281(3) 0.0000 0.8933(2) 0.019(2) Uani 1 2 d S . . S6 S 0.2414(3) 0.0000 0.9573(2) 0.022(2) Uani 1 2 d S . . S7 S 0.4916(3) 0.0000 0.7454(2) 0.021(2) Uani 1 2 d S . . S8 S 0.3994(3) 0.0000 0.1925(2) 0.020(2) Uani 1 2 d S . . S9 S 0.2873(3) 0.0000 0.1282(2) 0.020(2) Uani 1 2 d S . . S10 S 0.1780(3) 0.0000 0.0649(3) 0.021(2) Uani 1 2 d S . . S11 S 0.0310(3) 0.0000 0.3355(2) 0.0148(18) Uani 1 2 d S . . S12 S 0.0729(3) 0.0000 0.7239(2) 0.020(2) Uani 1 2 d S . . S13 S 0.1847(3) 0.0000 0.7847(2) 0.020(2) Uani 1 2 d S . . S14 S 0.2911(3) 0.0000 0.8434(3) 0.027(2) Uani 1 2 d S . . S15 S 0.4522(3) 0.0000 0.3607(2) 0.0150(18) Uani 1 2 d S . . S16 S 0.3425(3) 0.0000 0.3066(2) 0.020(2) Uani 1 2 d S . . S17 S 0.2381(3) 0.0000 0.2441(2) 0.0138(18) Uani 1 2 d S . . S18 S 0.0520(3) 0.0000 0.4801(3) 0.020(2) Uani 1 2 d S . . S19 S 0.1503(3) 0.0000 0.4615(2) 0.0134(18) Uani 1 2 d S . . S20 S 0.2683(3) 0.0000 0.4733(2) 0.0148(18) Uani 1 2 d S . . S21 S 0.3638(3) 0.0000 0.4538(3) 0.020(2) Uani 1 2 d S . . S22 S 0.4679(3) 0.0000 0.4468(3) 0.023(2) Uani 1 2 d S . . S23 S 0.1028(3) 0.0000 0.0957(2) 0.0158(18) Uani 1 2 d S . . S24 S 0.1385(3) 0.0000 0.1930(2) 0.0173(19) Uani 1 2 d S . . S25 S 0.1663(3) 0.0000 0.2964(2) 0.0156(18) Uani 1 2 d S . . S26 S 0.1864(3) 0.0000 0.3930(2) 0.021(2) Uani 1 2 d S . . S27 S 0.4714(3) 0.0000 0.9541(2) 0.019(2) Uani 1 2 d S . . S28 S 0.4455(3) 0.0000 0.8570(2) 0.021(2) Uani 1 2 d S . . S29 S 0.4075(3) 0.0000 0.7604(2) 0.0121(17) Uani 1 2 d S . . S30 S 0.3906(3) 0.0000 0.6620(2) 0.0149(18) Uani 1 2 d S . . S31 S 0.4404(3) 0.0000 0.5901(2) 0.0159(18) Uani 1 2 d S . . S32 S 0.2229(3) 0.0000 0.5975(2) 0.0146(18) Uani 1 2 d S . . S33 S 0.1236(4) 0.0000 0.6141(3) 0.028(2) Uani 1 2 d S . . S34 S 0.2380(3) 0.0000 0.6769(2) 0.019(2) Uani 1 2 d S . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Bi1 0.0167(7) 0.0141(6) 0.0203(7) 0.000 0.0125(6) 0.000 Bi2 0.0180(8) 0.0149(6) 0.0213(7) 0.000 0.0122(6) 0.000 Pb3 0.0171(8) 0.0154(6) 0.0224(7) 0.000 0.0093(6) 0.000 Pb4 0.0182(8) 0.0148(6) 0.0211(7) 0.000 0.0100(6) 0.000 Pb5 0.0174(8) 0.0149(6) 0.0223(7) 0.000 0.0101(6) 0.000 Pb6 0.0176(7) 0.0151(6) 0.0208(7) 0.000 0.0112(6) 0.000 Pb7 0.0175(8) 0.0169(6) 0.0236(7) 0.000 0.0105(6) 0.000 Bi8 0.0114(7) 0.0131(6) 0.0209(7) 0.000 0.0075(6) 0.000 Pb9 0.0151(7) 0.0147(6) 0.0221(7) 0.000 0.0083(6) 0.000 Bi10 0.0173(8) 0.0164(6) 0.0238(7) 0.000 0.0100(6) 0.000 Bi11 0.0175(8) 0.0154(6) 0.0254(7) 0.000 0.0099(6) 0.000 Bi12 0.0160(7) 0.0154(6) 0.0211(7) 0.000 0.0136(6) 0.000 Bi13 0.0123(7) 0.0141(6) 0.0220(7) 0.000 0.0075(6) 0.000 Pb14 0.0210(8) 0.0188(7) 0.0272(7) 0.000 0.0114(7) 0.000 Bi15 0.0149(7) 0.0135(6) 0.0185(6) 0.000 0.0064(6) 0.000 Bi16 0.0181(12) 0.0157(10) 0.0271(12) 0.000 0.0155(9) 0.000 Ag 0.0181(12) 0.0157(10) 0.0271(12) 0.000 0.0155(9) 0.000 Bi17 0.0181(8) 0.0184(7) 0.0249(7) 0.000 0.0121(6) 0.000 Pb18 0.0240(9) 0.0163(7) 0.0301(8) 0.000 0.0104(7) 0.000 Bi19 0.0173(8) 0.0141(6) 0.0262(7) 0.000 0.0126(6) 0.000 Bi20 0.0266(9) 0.0182(7) 0.0280(8) 0.000 0.0060(7) 0.000 Bi21 0.0211(8) 0.0162(6) 0.0270(7) 0.000 0.0117(7) 0.000 Pb22 0.0346(10) 0.0205(7) 0.0282(8) 0.000 0.0106(8) 0.000 Pb23 0.0225(8) 0.0146(6) 0.0293(8) 0.000 0.0077(7) 0.000 Pb24 0.0375(11) 0.0327(9) 0.0350(9) 0.000 0.0031(9) 0.000 Pb25 0.0234(9) 0.0218(8) 0.0509(11) 0.000 0.0000(9) 0.000 Pb26 0.0299(10) 0.0327(9) 0.0459(10) 0.000 0.0224(9) 0.000 Cu 0.028(5) 0.067(6) 0.021(4) 0.000 -0.003(4) 0.000 Cu1 0.017(3) 0.035(3) 0.040(3) 0.000 0.011(3) 0.000 Cu2 0.018(3) 0.020(2) 0.058(4) 0.000 0.018(3) 0.000 Cu3 0.014(3) 0.023(2) 0.048(3) 0.000 0.008(3) 0.000 S1 0.022(5) 0.007(4) 0.022(4) 0.000 0.020(4) 0.000 S2 0.003(4) 0.017(4) 0.026(5) 0.000 0.011(4) 0.000 S3 0.035(7) 0.022(5) 0.025(5) 0.000 0.012(5) 0.000 S4 0.011(5) 0.024(5) 0.016(4) 0.000 0.005(4) 0.000 S5 0.022(5) 0.018(4) 0.019(4) 0.000 0.013(4) 0.000 S6 0.029(6) 0.013(4) 0.030(5) 0.000 0.016(5) 0.000 S7 0.015(5) 0.024(5) 0.028(5) 0.000 0.012(4) 0.000 S8 0.025(6) 0.017(4) 0.025(5) 0.000 0.018(5) 0.000 S9 0.027(6) 0.011(4) 0.029(5) 0.000 0.019(5) 0.000 S10 0.012(5) 0.017(4) 0.043(6) 0.000 0.021(5) 0.000 S11 0.009(4) 0.011(4) 0.023(4) 0.000 0.002(4) 0.000 S12 0.031(6) 0.017(4) 0.013(4) 0.000 0.007(4) 0.000 S13 0.038(6) 0.012(4) 0.017(4) 0.000 0.020(5) 0.000 S14 0.030(6) 0.016(5) 0.042(6) 0.000 0.019(5) 0.000 S15 0.011(4) 0.017(4) 0.017(4) 0.000 0.004(4) 0.000 S16 0.026(6) 0.018(4) 0.019(4) 0.000 0.013(4) 0.000 S17 0.008(4) 0.013(4) 0.023(4) 0.000 0.008(4) 0.000 S18 0.008(4) 0.012(4) 0.038(6) 0.000 0.004(4) 0.000 S19 0.010(4) 0.011(4) 0.020(4) 0.000 0.006(4) 0.000 S20 0.018(5) 0.009(4) 0.020(4) 0.000 0.010(4) 0.000 S21 0.006(4) 0.018(4) 0.042(6) 0.000 0.018(4) 0.000 S22 0.013(5) 0.022(5) 0.038(6) 0.000 0.014(5) 0.000 S23 0.016(5) 0.017(4) 0.018(4) 0.000 0.011(4) 0.000 S24 0.016(5) 0.015(4) 0.023(4) 0.000 0.007(4) 0.000 S25 0.006(4) 0.020(4) 0.024(4) 0.000 0.008(4) 0.000 S26 0.015(5) 0.022(5) 0.027(5) 0.000 0.010(4) 0.000 S27 0.018(5) 0.021(4) 0.019(4) 0.000 0.007(4) 0.000 S28 0.017(5) 0.031(5) 0.017(4) 0.000 0.010(4) 0.000 S29 0.013(4) 0.013(4) 0.016(4) 0.000 0.013(4) 0.000 S30 0.016(5) 0.011(4) 0.023(4) 0.000 0.013(4) 0.000 S31 0.012(5) 0.018(4) 0.022(4) 0.000 0.010(4) 0.000 S32 0.018(5) 0.010(4) 0.017(4) 0.000 0.008(4) 0.000 S33 0.038(7) 0.024(5) 0.030(5) 0.000 0.024(5) 0.000 S34 0.029(6) 0.013(4) 0.019(4) 0.000 0.013(4) 0.000 _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Bi1 S1 2.578(9) 1_556 ? Bi1 S2 2.797(6) 7_546 ? Bi1 S2 2.797(6) 7_556 ? Bi1 S3 2.869(9) 7_556 ? Bi1 S3 2.869(8) 7_546 ? Bi1 S5 3.100(10) . ? Bi2 S2 2.706(9) . ? Bi2 S4 2.715(6) 7_556 ? Bi2 S4 2.715(6) 7_546 ? Bi2 S5 3.013(8) 7_546 ? Bi2 S5 3.013(8) 7_556 ? Bi2 S8 3.063(10) . ? Pb3 S5 2.891(8) 7_556 ? Pb3 S5 2.891(8) 7_546 ? Pb3 S9 2.924(10) . ? Pb3 S6 2.990(8) 7_546 ? Pb3 S6 2.990(8) 7_556 ? Pb3 S3 3.111(12) . ? Pb4 S10 2.713(11) . ? Pb4 S6 2.845(8) 7_556 ? Pb4 S6 2.845(8) 7_546 ? Pb4 S3 2.944(9) 7_545 ? Pb4 S3 2.944(9) 7 ? Pb5 S7 2.778(7) 3_445 ? Pb5 S7 2.778(7) 3_455 ? Pb5 S4 2.873(10) . ? Pb5 S12 2.890(11) . ? Pb5 S8 2.999(8) 7_556 ? Pb5 S8 2.999(8) 7_546 ? Pb6 S13 2.882(10) . ? Pb6 S5 2.890(10) . ? Pb6 S8 2.907(8) 7_546 ? Pb6 S8 2.907(8) 7_556 ? Pb6 S9 2.949(8) 7_556 ? Pb6 S9 2.949(8) 7_546 ? Pb7 S14 2.842(12) . ? Pb7 S10 2.858(8) 7_556 ? Pb7 S10 2.858(8) 7_546 ? Pb7 S9 2.942(8) 7_546 ? Pb7 S9 2.942(8) 7_556 ? Pb7 S6 2.998(10) . ? Bi8 S11 2.671(6) 3 ? Bi8 S11 2.671(6) 3_545 ? Bi8 S7 2.829(10) 5_656 ? Bi8 S15 2.841(10) . ? Bi8 S12 2.974(8) 7_546 ? Bi8 S12 2.974(8) 7_556 ? Pb9 S12 2.888(8) 7_556 ? Pb9 S12 2.888(8) 7_546 ? Pb9 S8 2.924(10) . ? Pb9 S13 2.929(8) 7_546 ? Pb9 S13 2.929(8) 7_556 ? Pb9 S16 3.079(10) . ? Bi10 S14 2.733(8) 7_546 ? Bi10 S14 2.733(8) 7_556 ? Bi10 S17 2.789(10) . ? Bi10 S13 2.961(9) 7_556 ? Bi10 S13 2.961(9) 7_546 ? Bi10 S9 3.127(10) . ? Bi11 S33 2.595(11) . ? Bi11 S15 2.752(6) 7_546 ? Bi11 S15 2.752(6) 7_556 ? Bi11 S16 2.961(8) 7_556 ? Bi11 S16 2.961(8) 7_546 ? Bi11 S12 3.092(10) . ? Bi12 S34 2.585(10) . ? Bi12 S17 2.788(6) 7_556 ? Bi12 S17 2.788(6) 7_546 ? Bi12 S16 2.894(8) 7_546 ? Bi12 S16 2.894(8) 7_556 ? Bi12 S13 3.081(9) . ? Bi13 S31 2.625(10) . ? Bi13 S18 2.738(7) 7_556 ? Bi13 S18 2.738(7) 7_546 ? Bi13 S19 2.972(7) 7_546 ? Bi13 S19 2.972(7) 7_556 ? Bi13 S21 3.078(11) . ? Pb14 S20 2.843(9) . ? Pb14 S19 2.912(7) 7_556 ? Pb14 S19 2.912(7) 7_546 ? Pb14 S20 3.035(8) 7_546 ? Pb14 S20 3.035(8) 7_556 ? Bi15 S32 2.578(9) . ? Bi15 S21 2.803(7) 7_546 ? Bi15 S21 2.803(6) 7_556 ? Bi15 S20 2.844(7) 7_556 ? Bi15 S20 2.844(7) 7_546 ? Bi15 S19 3.112(9) . ? Bi16 S33 2.675(12) . ? Bi16 S22 2.756(7) 7_546 ? Bi16 S22 2.756(7) 7_556 ? Bi16 S18 2.942(11) . ? Bi16 S21 2.947(7) 7_556 ? Bi16 S21 2.947(7) 7_546 ? Bi17 S28 2.632(11) . ? Bi17 S23 2.845(6) 7_556 ? Bi17 S23 2.845(6) 7_546 ? Bi17 S24 2.868(7) 7_546 ? Bi17 S24 2.868(7) 7_556 ? Bi17 S14 3.001(12) . ? Pb18 S29 2.687(10) . ? Pb18 S25 2.882(7) 7_546 ? Pb18 S25 2.882(7) 7_556 ? Pb18 S24 3.102(7) 7_556 ? Pb18 S24 3.102(7) 7_546 ? Bi19 S30 2.583(10) . ? Bi19 S26 2.745(7) 7_546 ? Bi19 S26 2.745(7) 7_556 ? Bi19 S25 2.981(7) 7_556 ? Bi19 S25 2.981(7) 7_546 ? Bi20 S23 2.663(10) . ? Bi20 S27 2.691(6) 7_546 ? Bi20 S27 2.691(6) 7_556 ? Bi20 S28 3.087(7) 7_556 ? Bi20 S28 3.087(7) 7_546 ? Bi21 S24 2.626(10) . ? Bi21 S29 2.811(6) 7_556 ? Bi21 S29 2.811(6) 7_546 ? Bi21 S28 2.889(7) 7_546 ? Bi21 S28 2.889(7) 7_556 ? Pb22 S30 2.886(7) 7_556 ? Pb22 S30 2.886(7) 7_546 ? Pb22 S11 3.063(10) . ? Pb23 S11 2.905(9) . ? Pb23 S31 2.915(7) 7_546 ? Pb23 S31 2.915(7) 7_556 ? Pb23 S30 3.059(7) 7_546 ? Pb23 S30 3.059(7) 7_556 ? Pb23 S26 3.092(11) . ? Pb23 S19 3.113(9) . ? Pb24 S1 3.015(8) 7_556 ? Pb24 S1 3.015(7) 7_546 ? Pb24 S10 3.112(8) 7_546 ? Pb24 S10 3.112(8) 7_556 ? Pb24 Cu1 3.157(6) 1_556 ? Pb25 S18 2.906(10) . ? Pb25 S31 2.980(7) 7_556 ? Pb25 S31 2.980(7) 7_546 ? Pb25 S22 3.026(8) 3_455 ? Pb25 S22 3.026(8) 3_445 ? Pb26 S33 2.874(9) 7_556 ? Pb26 S33 2.874(9) 7_546 ? Pb26 S32 3.109(8) 7_546 ? Pb26 S32 3.109(8) 7_556 ? Cu S22 2.240(11) 5_656 ? Cu S22 2.240(11) . ? Cu1 S27 2.270(11) 5_656 ? Cu1 S1 2.359(6) 7_545 ? Cu1 S1 2.359(6) 7 ? Cu1 S27 2.485(11) 1_554 ? Cu1 Cu1 2.760(12) 5_655 ? Cu1 Pb24 3.157(6) 1_554 ? Cu2 S34 2.312(6) 7_556 ? Cu2 S34 2.312(6) 7_546 ? Cu2 S25 2.313(11) . ? Cu3 S26 2.277(12) 5_656 ? Cu3 S32 2.328(6) 3_545 ? Cu3 S32 2.328(6) 3 ? Cu3 S20 2.606(11) 5_656 ? S1 Cu1 2.359(6) 7_545 ? S1 Cu1 2.359(6) 7 ? S1 Bi1 2.578(9) 1_554 ? S1 Pb24 3.015(7) 7_556 ? S1 Pb24 3.015(7) 7_546 ? S2 Bi1 2.797(6) 7_546 ? S2 Bi1 2.797(6) 7_556 ? S3 Bi1 2.869(8) 7_556 ? S3 Bi1 2.869(8) 7_546 ? S3 Pb4 2.944(9) 7_545 ? S3 Pb4 2.944(9) 7 ? S4 Bi2 2.715(6) 7_556 ? S4 Bi2 2.715(6) 7_546 ? S5 Pb3 2.891(8) 7_556 ? S5 Pb3 2.891(8) 7_546 ? S5 Bi2 3.013(8) 7_546 ? S5 Bi2 3.013(8) 7_556 ? S6 Pb4 2.845(8) 7_556 ? S6 Pb4 2.845(8) 7_546 ? S6 Pb3 2.990(8) 7_546 ? S6 Pb3 2.990(8) 7_556 ? S7 Pb5 2.778(7) 3 ? S7 Pb5 2.778(7) 3_545 ? S7 Bi8 2.829(10) 5_656 ? S8 Pb6 2.907(8) 7_546 ? S8 Pb6 2.907(8) 7_556 ? S8 Pb5 2.999(8) 7_556 ? S8 Pb5 2.999(8) 7_546 ? S9 Pb7 2.942(8) 7_546 ? S9 Pb7 2.942(8) 7_556 ? S9 Pb6 2.949(8) 7_556 ? S9 Pb6 2.949(8) 7_546 ? S10 Pb7 2.858(8) 7_556 ? S10 Pb7 2.858(8) 7_546 ? S10 Pb24 3.112(8) 7_546 ? S10 Pb24 3.112(8) 7_556 ? S11 Bi8 2.671(6) 3_445 ? S11 Bi8 2.671(6) 3_455 ? S12 Pb9 2.888(8) 7_556 ? S12 Pb9 2.888(8) 7_546 ? S12 Bi8 2.974(8) 7_546 ? S12 Bi8 2.974(8) 7_556 ? S13 Pb9 2.929(8) 7_546 ? S13 Pb9 2.929(8) 7_556 ? S13 Bi10 2.961(9) 7_556 ? S13 Bi10 2.961(9) 7_546 ? S14 Bi10 2.733(8) 7_546 ? S14 Bi10 2.733(8) 7_556 ? S15 Bi11 2.752(6) 7_546 ? S15 Bi11 2.752(6) 7_556 ? S16 Bi12 2.894(8) 7_546 ? S16 Bi12 2.894(8) 7_556 ? S16 Bi11 2.961(8) 7_556 ? S16 Bi11 2.961(8) 7_546 ? S17 Bi12 2.788(6) 7_556 ? S17 Bi12 2.788(6) 7_546 ? S18 Bi13 2.738(7) 7_556 ? S18 Bi13 2.738(7) 7_546 ? S19 Pb14 2.912(7) 7_556 ? S19 Pb14 2.912(7) 7_546 ? S19 Bi13 2.972(7) 7_546 ? S19 Bi13 2.972(7) 7_556 ? S20 Cu3 2.606(11) 5_656 ? S20 Bi15 2.844(7) 7_556 ? S20 Bi15 2.844(7) 7_546 ? S20 Pb14 3.035(8) 7_546 ? S20 Pb14 3.035(8) 7_556 ? S21 Bi15 2.803(6) 7_546 ? S21 Bi15 2.803(6) 7_556 ? S21 Ag 2.947(7) 7_556 ? S21 Bi16 2.947(7) 7_556 ? S21 Ag 2.947(7) 7_546 ? S21 Bi16 2.947(7) 7_546 ? S22 Ag 2.756(7) 7_546 ? S22 Bi16 2.756(7) 7_546 ? S22 Ag 2.756(7) 7_556 ? S22 Bi16 2.756(7) 7_556 ? S22 Pb25 3.026(8) 3_545 ? S22 Pb25 3.026(8) 3 ? S23 Bi17 2.845(6) 7_556 ? S23 Bi17 2.845(6) 7_546 ? S24 Bi17 2.868(7) 7_546 ? S24 Bi17 2.868(7) 7_556 ? S24 Pb18 3.102(7) 7_556 ? S24 Pb18 3.102(7) 7_546 ? S25 Pb18 2.882(7) 7_546 ? S25 Pb18 2.882(7) 7_556 ? S25 Bi19 2.981(7) 7_556 ? S25 Bi19 2.981(7) 7_546 ? S26 Cu3 2.277(12) 5_656 ? S26 Bi19 2.745(7) 7_546 ? S26 Bi19 2.745(7) 7_556 ? S27 Cu1 2.270(11) 5_656 ? S27 Cu1 2.485(11) 1_556 ? S27 Bi20 2.691(6) 7_546 ? S27 Bi20 2.691(6) 7_556 ? S28 Bi21 2.889(7) 7_546 ? S28 Bi21 2.889(7) 7_556 ? S28 Bi20 3.087(7) 7_556 ? S28 Bi20 3.087(7) 7_546 ? S29 Bi21 2.811(6) 7_556 ? S29 Bi21 2.811(6) 7_546 ? S30 Pb22 2.886(7) 7_556 ? S30 Pb22 2.886(7) 7_546 ? S30 Pb23 3.059(7) 7_546 ? S30 Pb23 3.059(7) 7_556 ? S31 Pb23 2.915(7) 7_546 ? S31 Pb23 2.915(7) 7_556 ? S31 Pb25 2.980(7) 7_556 ? S31 Pb25 2.980(7) 7_546 ? S32 Cu3 2.328(6) 3_455 ? S32 Cu3 2.328(6) 3_445 ? S32 Pb26 3.109(8) 7_546 ? S32 Pb26 3.109(8) 7_556 ? S33 Pb26 2.874(9) 7_556 ? S33 Pb26 2.874(9) 7_546 ? S34 Cu2 2.312(6) 7_556 ? S34 Cu2 2.312(6) 7_546 ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag S1 Bi1 S2 91.3(3) 1_556 7_546 ? S1 Bi1 S2 91.3(2) 1_556 7_556 ? S2 Bi1 S2 92.9(3) 7_546 7_556 ? S1 Bi1 S3 91.7(3) 1_556 7_556 ? S2 Bi1 S3 176.7(3) 7_546 7_556 ? S2 Bi1 S3 88.6(2) 7_556 7_556 ? S1 Bi1 S3 91.7(3) 1_556 7_546 ? S2 Bi1 S3 88.6(2) 7_546 7_546 ? S2 Bi1 S3 176.7(3) 7_556 7_546 ? S3 Bi1 S3 89.9(3) 7_556 7_546 ? S1 Bi1 S5 178.2(3) 1_556 . ? S2 Bi1 S5 87.4(2) 7_546 . ? S2 Bi1 S5 87.4(2) 7_556 . ? S3 Bi1 S5 89.6(3) 7_556 . ? S3 Bi1 S5 89.6(3) 7_546 . ? S2 Bi2 S4 94.2(2) . 7_556 ? S2 Bi2 S4 94.2(2) . 7_546 ? S4 Bi2 S4 96.5(3) 7_556 7_546 ? S2 Bi2 S5 90.9(2) . 7_546 ? S4 Bi2 S5 172.0(3) 7_556 7_546 ? S4 Bi2 S5 89.2(2) 7_546 7_546 ? S2 Bi2 S5 90.9(2) . 7_556 ? S4 Bi2 S5 89.2(2) 7_556 7_556 ? S4 Bi2 S5 172.0(3) 7_546 7_556 ? S5 Bi2 S5 84.5(3) 7_546 7_556 ? S2 Bi2 S8 173.7(3) . . ? S4 Bi2 S8 90.0(3) 7_556 . ? S4 Bi2 S8 90.0(3) 7_546 . ? S5 Bi2 S8 84.4(2) 7_546 . ? S5 Bi2 S8 84.4(2) 7_556 . ? S5 Pb3 S5 89.0(3) 7_556 7_546 ? S5 Pb3 S9 90.1(3) 7_556 . ? S5 Pb3 S9 90.1(3) 7_546 . ? S5 Pb3 S6 176.5(3) 7_556 7_546 ? S5 Pb3 S6 92.7(2) 7_546 7_546 ? S9 Pb3 S6 86.9(3) . 7_546 ? S5 Pb3 S6 92.7(2) 7_556 7_556 ? S5 Pb3 S6 176.5(3) 7_546 7_556 ? S9 Pb3 S6 86.9(3) . 7_556 ? S6 Pb3 S6 85.3(3) 7_546 7_556 ? S5 Pb3 S3 89.0(3) 7_556 . ? S5 Pb3 S3 89.0(3) 7_546 . ? S9 Pb3 S3 178.7(3) . . ? S6 Pb3 S3 94.0(3) 7_546 . ? S6 Pb3 S3 94.0(3) 7_556 . ? S10 Pb4 S6 92.1(3) . 7_556 ? S10 Pb4 S6 92.1(3) . 7_546 ? S6 Pb4 S6 90.8(3) 7_556 7_546 ? S10 Pb4 S3 89.1(3) . 7_545 ? S6 Pb4 S3 177.7(3) 7_556 7_545 ? S6 Pb4 S3 91.1(2) 7_546 7_545 ? S10 Pb4 S3 89.1(3) . 7 ? S6 Pb4 S3 91.1(2) 7_556 7 ? S6 Pb4 S3 177.7(3) 7_546 7 ? S3 Pb4 S3 87.0(3) 7_545 7 ? S7 Pb5 S7 93.7(3) 3_445 3_455 ? S7 Pb5 S4 95.6(3) 3_445 . ? S7 Pb5 S4 95.6(3) 3_455 . ? S7 Pb5 S12 90.1(3) 3_445 . ? S7 Pb5 S12 90.1(3) 3_455 . ? S4 Pb5 S12 171.7(3) . . ? S7 Pb5 S8 173.9(3) 3_445 7_556 ? S7 Pb5 S8 90.5(2) 3_455 7_556 ? S4 Pb5 S8 88.3(2) . 7_556 ? S12 Pb5 S8 85.5(2) . 7_556 ? S7 Pb5 S8 90.5(2) 3_445 7_546 ? S7 Pb5 S8 173.9(3) 3_455 7_546 ? S4 Pb5 S8 88.3(2) . 7_546 ? S12 Pb5 S8 85.5(2) . 7_546 ? S8 Pb5 S8 85.0(3) 7_556 7_546 ? S13 Pb6 S5 179.4(3) . . ? S13 Pb6 S8 90.9(3) . 7_546 ? S5 Pb6 S8 89.5(2) . 7_546 ? S13 Pb6 S8 90.9(3) . 7_556 ? S5 Pb6 S8 89.5(2) . 7_556 ? S8 Pb6 S8 88.4(3) 7_546 7_556 ? S13 Pb6 S9 90.0(3) . 7_556 ? S5 Pb6 S9 89.6(3) . 7_556 ? S8 Pb6 S9 178.8(3) 7_546 7_556 ? S8 Pb6 S9 92.4(2) 7_556 7_556 ? S13 Pb6 S9 90.0(3) . 7_546 ? S5 Pb6 S9 89.6(3) . 7_546 ? S8 Pb6 S9 92.4(2) 7_546 7_546 ? S8 Pb6 S9 178.8(3) 7_556 7_546 ? S9 Pb6 S9 86.8(3) 7_556 7_546 ? S14 Pb7 S10 97.6(3) . 7_556 ? S14 Pb7 S10 97.6(3) . 7_546 ? S10 Pb7 S10 90.3(3) 7_556 7_546 ? S14 Pb7 S9 89.5(3) . 7_546 ? S10 Pb7 S9 172.6(3) 7_556 7_546 ? S10 Pb7 S9 90.9(2) 7_546 7_546 ? S14 Pb7 S9 89.5(3) . 7_556 ? S10 Pb7 S9 90.9(2) 7_556 7_556 ? S10 Pb7 S9 172.6(3) 7_546 7_556 ? S9 Pb7 S9 87.1(3) 7_546 7_556 ? S14 Pb7 S6 174.5(3) . . ? S10 Pb7 S6 86.2(3) 7_556 . ? S10 Pb7 S6 86.2(3) 7_546 . ? S9 Pb7 S6 86.5(3) 7_546 . ? S9 Pb7 S6 86.5(3) 7_556 . ? S11 Bi8 S11 98.7(3) 3 3_545 ? S11 Bi8 S7 90.7(3) 3 5_656 ? S11 Bi8 S7 90.7(3) 3_545 5_656 ? S11 Bi8 S15 93.4(2) 3 . ? S11 Bi8 S15 93.4(2) 3_545 . ? S7 Bi8 S15 173.8(3) 5_656 . ? S11 Bi8 S12 173.4(2) 3 7_546 ? S11 Bi8 S12 87.7(2) 3_545 7_546 ? S7 Bi8 S12 87.4(3) 5_656 7_546 ? S15 Bi8 S12 88.0(2) . 7_546 ? S11 Bi8 S12 87.7(2) 3 7_556 ? S11 Bi8 S12 173.4(2) 3_545 7_556 ? S7 Bi8 S12 87.4(3) 5_656 7_556 ? S15 Bi8 S12 88.0(2) . 7_556 ? S12 Bi8 S12 85.9(3) 7_546 7_556 ? S12 Pb9 S12 89.1(3) 7_556 7_546 ? S12 Pb9 S8 87.0(3) 7_556 . ? S12 Pb9 S8 87.0(3) 7_546 . ? S12 Pb9 S13 176.5(3) 7_556 7_546 ? S12 Pb9 S13 91.6(2) 7_546 7_546 ? S8 Pb9 S13 89.6(2) . 7_546 ? S12 Pb9 S13 91.6(2) 7_556 7_556 ? S12 Pb9 S13 176.5(3) 7_546 7_556 ? S8 Pb9 S13 89.6(2) . 7_556 ? S13 Pb9 S13 87.6(3) 7_546 7_556 ? S12 Pb9 S16 92.5(2) 7_556 . ? S12 Pb9 S16 92.5(2) 7_546 . ? S8 Pb9 S16 179.2(3) . . ? S13 Pb9 S16 90.9(2) 7_546 . ? S13 Pb9 S16 90.9(2) 7_556 . ? S14 Bi10 S14 95.7(4) 7_546 7_556 ? S14 Bi10 S17 97.1(3) 7_546 . ? S14 Bi10 S17 97.1(3) 7_556 . ? S14 Bi10 S13 171.7(3) 7_546 7_556 ? S14 Bi10 S13 88.5(2) 7_556 7_556 ? S17 Bi10 S13 89.4(2) . 7_556 ? S14 Bi10 S13 88.5(2) 7_546 7_546 ? S14 Bi10 S13 171.7(3) 7_556 7_546 ? S17 Bi10 S13 89.4(2) . 7_546 ? S13 Bi10 S13 86.4(3) 7_556 7_546 ? S14 Bi10 S9 87.8(3) 7_546 . ? S14 Bi10 S9 87.8(3) 7_556 . ? S17 Bi10 S9 172.7(3) . . ? S13 Bi10 S9 85.2(2) 7_556 . ? S13 Bi10 S9 85.2(2) 7_546 . ? S33 Bi11 S15 94.3(3) . 7_546 ? S33 Bi11 S15 94.3(3) . 7_556 ? S15 Bi11 S15 94.8(3) 7_546 7_556 ? S33 Bi11 S16 87.5(3) . 7_556 ? S15 Bi11 S16 175.3(2) 7_546 7_556 ? S15 Bi11 S16 89.4(2) 7_556 7_556 ? S33 Bi11 S16 87.5(3) . 7_546 ? S15 Bi11 S16 89.4(2) 7_546 7_546 ? S15 Bi11 S16 175.3(2) 7_556 7_546 ? S16 Bi11 S16 86.4(3) 7_556 7_546 ? S33 Bi11 S12 177.7(4) . . ? S15 Bi11 S12 87.3(2) 7_546 . ? S15 Bi11 S12 87.3(2) 7_556 . ? S16 Bi11 S12 90.8(2) 7_556 . ? S16 Bi11 S12 90.8(2) 7_546 . ? S34 Bi12 S17 91.2(3) . 7_556 ? S34 Bi12 S17 91.2(3) . 7_546 ? S17 Bi12 S17 93.3(3) 7_556 7_546 ? S34 Bi12 S16 90.2(3) . 7_546 ? S17 Bi12 S16 177.4(2) 7_556 7_546 ? S17 Bi12 S16 88.9(2) 7_546 7_546 ? S34 Bi12 S16 90.2(3) . 7_556 ? S17 Bi12 S16 88.9(2) 7_556 7_556 ? S17 Bi12 S16 177.4(2) 7_546 7_556 ? S16 Bi12 S16 88.9(3) 7_546 7_556 ? S34 Bi12 S13 177.5(3) . . ? S17 Bi12 S13 87.1(2) 7_556 . ? S17 Bi12 S13 87.1(2) 7_546 . ? S16 Bi12 S13 91.6(3) 7_546 . ? S16 Bi12 S13 91.6(2) 7_556 . ? S31 Bi13 S18 88.9(3) . 7_556 ? S31 Bi13 S18 88.9(3) . 7_546 ? S18 Bi13 S18 95.5(3) 7_556 7_546 ? S31 Bi13 S19 90.1(2) . 7_546 ? S18 Bi13 S19 175.1(2) 7_556 7_546 ? S18 Bi13 S19 89.3(2) 7_546 7_546 ? S31 Bi13 S19 90.1(2) . 7_556 ? S18 Bi13 S19 89.3(2) 7_556 7_556 ? S18 Bi13 S19 175.1(2) 7_546 7_556 ? S19 Bi13 S19 86.0(3) 7_546 7_556 ? S31 Bi13 S21 175.8(3) . . ? S18 Bi13 S21 88.3(3) 7_556 . ? S18 Bi13 S21 88.3(3) 7_546 . ? S19 Bi13 S21 93.0(2) 7_546 . ? S19 Bi13 S21 93.0(2) 7_556 . ? S20 Pb14 S19 87.6(2) . 7_556 ? S20 Pb14 S19 87.6(2) . 7_546 ? S19 Pb14 S19 88.2(3) 7_556 7_546 ? S20 Pb14 S20 77.1(2) . 7_546 ? S19 Pb14 S20 164.7(2) 7_556 7_546 ? S19 Pb14 S20 92.01(19) 7_546 7_546 ? S20 Pb14 S20 77.1(2) . 7_556 ? S19 Pb14 S20 92.01(19) 7_556 7_556 ? S19 Pb14 S20 164.7(2) 7_546 7_556 ? S20 Pb14 S20 83.8(3) 7_546 7_556 ? S32 Bi15 S21 91.8(3) . 7_546 ? S32 Bi15 S21 91.8(3) . 7_556 ? S21 Bi15 S21 92.6(3) 7_546 7_556 ? S32 Bi15 S20 88.6(2) . 7_556 ? S21 Bi15 S20 179.0(2) 7_546 7_556 ? S21 Bi15 S20 88.2(2) 7_556 7_556 ? S32 Bi15 S20 88.6(2) . 7_546 ? S21 Bi15 S20 88.2(2) 7_546 7_546 ? S21 Bi15 S20 179.0(2) 7_556 7_546 ? S20 Bi15 S20 90.9(3) 7_556 7_546 ? S32 Bi15 S19 169.3(3) . . ? S21 Bi15 S19 95.6(3) 7_546 . ? S21 Bi15 S19 95.6(3) 7_556 . ? S20 Bi15 S19 83.9(2) 7_556 . ? S20 Bi15 S19 83.9(2) 7_546 . ? S33 Bi16 S22 98.8(3) . 7_546 ? S33 Bi16 S22 98.8(3) . 7_556 ? S22 Bi16 S22 94.6(3) 7_546 7_556 ? S33 Bi16 S18 166.6(3) . . ? S22 Bi16 S18 90.2(3) 7_546 . ? S22 Bi16 S18 90.2(3) 7_556 . ? S33 Bi16 S21 83.1(3) . 7_556 ? S22 Bi16 S21 175.4(3) 7_546 7_556 ? S22 Bi16 S21 89.2(2) 7_556 7_556 ? S18 Bi16 S21 87.1(3) . 7_556 ? S33 Bi16 S21 83.1(3) . 7_546 ? S22 Bi16 S21 89.2(2) 7_546 7_546 ? S22 Bi16 S21 175.4(3) 7_556 7_546 ? S18 Bi16 S21 87.1(3) . 7_546 ? S21 Bi16 S21 86.9(3) 7_556 7_546 ? S28 Bi17 S23 86.2(3) . 7_556 ? S28 Bi17 S23 86.2(3) . 7_546 ? S23 Bi17 S23 90.9(3) 7_556 7_546 ? S28 Bi17 S24 86.8(3) . 7_546 ? S23 Bi17 S24 173.0(3) 7_556 7_546 ? S23 Bi17 S24 89.19(19) 7_546 7_546 ? S28 Bi17 S24 86.8(3) . 7_556 ? S23 Bi17 S24 89.19(19) 7_556 7_556 ? S23 Bi17 S24 173.0(3) 7_546 7_556 ? S24 Bi17 S24 89.9(3) 7_546 7_556 ? S28 Bi17 S14 170.9(3) . . ? S23 Bi17 S14 100.2(3) 7_556 . ? S23 Bi17 S14 100.2(3) 7_546 . ? S24 Bi17 S14 86.7(3) 7_546 . ? S24 Bi17 S14 86.7(3) 7_556 . ? S29 Pb18 S25 82.3(2) . 7_546 ? S29 Pb18 S25 82.3(2) . 7_556 ? S25 Pb18 S25 89.4(3) 7_546 7_556 ? S29 Pb18 S24 78.3(2) . 7_556 ? S25 Pb18 S24 160.3(3) 7_546 7_556 ? S25 Pb18 S24 91.30(19) 7_556 7_556 ? S29 Pb18 S24 78.3(2) . 7_546 ? S25 Pb18 S24 91.30(19) 7_546 7_546 ? S25 Pb18 S24 160.3(3) 7_556 7_546 ? S24 Pb18 S24 81.6(2) 7_556 7_546 ? S30 Bi19 S26 88.0(3) . 7_546 ? S30 Bi19 S26 88.0(3) . 7_556 ? S26 Bi19 S26 95.1(3) 7_546 7_556 ? S30 Bi19 S25 85.8(2) . 7_556 ? S26 Bi19 S25 172.2(3) 7_546 7_556 ? S26 Bi19 S25 89.3(2) 7_556 7_556 ? S30 Bi19 S25 85.8(2) . 7_546 ? S26 Bi19 S25 89.3(2) 7_546 7_546 ? S26 Bi19 S25 172.2(3) 7_556 7_546 ? S25 Bi19 S25 85.7(3) 7_556 7_546 ? S23 Bi20 S27 83.2(3) . 7_546 ? S23 Bi20 S27 83.2(3) . 7_556 ? S27 Bi20 S27 97.7(3) 7_546 7_556 ? S23 Bi20 S28 80.9(2) . 7_556 ? S27 Bi20 S28 162.4(3) 7_546 7_556 ? S27 Bi20 S28 88.0(2) 7_556 7_556 ? S23 Bi20 S28 80.9(2) . 7_546 ? S27 Bi20 S28 88.0(2) 7_546 7_546 ? S27 Bi20 S28 162.4(3) 7_556 7_546 ? S28 Bi20 S28 82.1(2) 7_556 7_546 ? S24 Bi21 S29 84.8(2) . 7_556 ? S24 Bi21 S29 84.8(2) . 7_546 ? S29 Bi21 S29 92.3(3) 7_556 7_546 ? S24 Bi21 S28 86.5(3) . 7_546 ? S29 Bi21 S28 171.1(3) 7_556 7_546 ? S29 Bi21 S28 88.66(18) 7_546 7_546 ? S24 Bi21 S28 86.5(3) . 7_556 ? S29 Bi21 S28 88.66(18) 7_556 7_556 ? S29 Bi21 S28 171.1(3) 7_546 7_556 ? S28 Bi21 S28 89.1(3) 7_546 7_556 ? S30 Pb22 S30 89.2(3) 7_556 7_546 ? S30 Pb22 S11 72.9(2) 7_556 . ? S30 Pb22 S11 72.9(2) 7_546 . ? S11 Pb23 S31 78.3(2) . 7_546 ? S11 Pb23 S31 78.3(2) . 7_556 ? S31 Pb23 S31 88.1(3) 7_546 7_556 ? S11 Pb23 S30 72.7(2) . 7_546 ? S31 Pb23 S30 87.3(2) 7_546 7_546 ? S31 Pb23 S30 151.0(3) 7_556 7_546 ? S11 Pb23 S30 72.7(2) . 7_556 ? S31 Pb23 S30 151.0(3) 7_546 7_556 ? S31 Pb23 S30 87.3(2) 7_556 7_556 ? S30 Pb23 S30 83.0(2) 7_546 7_556 ? S11 Pb23 S26 135.1(3) . . ? S31 Pb23 S26 129.12(18) 7_546 . ? S31 Pb23 S26 129.12(18) 7_556 . ? S30 Pb23 S26 74.0(2) 7_546 . ? S30 Pb23 S26 74.0(2) 7_556 . ? S11 Pb23 S19 152.8(3) . . ? S31 Pb23 S19 82.3(2) 7_546 . ? S31 Pb23 S19 82.3(2) 7_556 . ? S30 Pb23 S19 125.31(19) 7_546 . ? S30 Pb23 S19 125.31(19) 7_556 . ? S26 Pb23 S19 72.1(3) . . ? S1 Pb24 S1 84.5(3) 7_556 7_546 ? S1 Pb24 S10 151.1(3) 7_556 7_546 ? S1 Pb24 S10 90.0(2) 7_546 7_546 ? S1 Pb24 S10 90.0(2) 7_556 7_556 ? S1 Pb24 S10 151.1(3) 7_546 7_556 ? S10 Pb24 S10 81.2(3) 7_546 7_556 ? S1 Pb24 Cu1 44.86(15) 7_556 1_556 ? S1 Pb24 Cu1 44.86(15) 7_546 1_556 ? S10 Pb24 Cu1 134.74(17) 7_546 1_556 ? S10 Pb24 Cu1 134.74(17) 7_556 1_556 ? S18 Pb25 S31 79.3(2) . 7_556 ? S18 Pb25 S31 79.3(2) . 7_546 ? S31 Pb25 S31 85.7(3) 7_556 7_546 ? S18 Pb25 S22 75.4(3) . 3_455 ? S31 Pb25 S22 89.6(2) 7_556 3_455 ? S31 Pb25 S22 154.7(3) 7_546 3_455 ? S18 Pb25 S22 75.4(3) . 3_445 ? S31 Pb25 S22 154.7(3) 7_556 3_445 ? S31 Pb25 S22 89.6(2) 7_546 3_445 ? S22 Pb25 S22 84.1(3) 3_455 3_445 ? S33 Pb26 S33 89.7(4) 7_556 7_546 ? S33 Pb26 S32 144.5(3) 7_556 7_546 ? S33 Pb26 S32 84.0(2) 7_546 7_546 ? S33 Pb26 S32 84.0(2) 7_556 7_556 ? S33 Pb26 S32 144.5(3) 7_546 7_556 ? S32 Pb26 S32 81.4(2) 7_546 7_556 ? S22 Cu S22 180.000(2) 5_656 . ? S27 Cu1 S1 116.8(3) 5_656 7_545 ? S27 Cu1 S1 116.8(3) 5_656 7 ? S1 Cu1 S1 118.4(5) 7_545 7 ? S27 Cu1 S27 109.2(3) 5_656 1_554 ? S1 Cu1 S27 94.5(3) 7_545 1_554 ? S1 Cu1 S27 94.5(3) 7 1_554 ? S27 Cu1 Cu1 58.3(3) 5_656 5_655 ? S1 Cu1 Cu1 116.3(3) 7_545 5_655 ? S1 Cu1 Cu1 116.3(3) 7 5_655 ? S27 Cu1 Cu1 51.0(3) 1_554 5_655 ? S27 Cu1 Pb24 175.7(4) 5_656 1_554 ? S1 Cu1 Pb24 64.4(3) 7_545 1_554 ? S1 Cu1 Pb24 64.4(3) 7 1_554 ? S27 Cu1 Pb24 66.5(3) 1_554 1_554 ? Cu1 Cu1 Pb24 117.5(3) 5_655 1_554 ? S34 Cu2 S34 122.4(5) 7_556 7_546 ? S34 Cu2 S25 117.3(3) 7_556 . ? S34 Cu2 S25 117.3(3) 7_546 . ? S26 Cu3 S32 113.9(3) 5_656 3_545 ? S26 Cu3 S32 113.9(3) 5_656 3 ? S32 Cu3 S32 121.0(5) 3_545 3 ? S26 Cu3 S20 103.4(4) 5_656 5_656 ? S32 Cu3 S20 100.3(3) 3_545 5_656 ? S32 Cu3 S20 100.3(3) 3 5_656 ? Cu1 S1 Cu1 118.4(5) 7_545 7 ? Cu1 S1 Bi1 105.3(3) 7_545 1_554 ? Cu1 S1 Bi1 105.3(3) 7 1_554 ? Cu1 S1 Pb24 145.6(4) 7_545 7_556 ? Cu1 S1 Pb24 70.74(17) 7 7_556 ? Bi1 S1 Pb24 103.3(3) 1_554 7_556 ? Cu1 S1 Pb24 70.74(17) 7_545 7_546 ? Cu1 S1 Pb24 145.6(4) 7 7_546 ? Bi1 S1 Pb24 103.3(3) 1_554 7_546 ? Pb24 S1 Pb24 84.5(3) 7_556 7_546 ? Bi2 S2 Bi1 96.8(2) . 7_546 ? Bi2 S2 Bi1 96.8(2) . 7_556 ? Bi1 S2 Bi1 92.9(3) 7_546 7_556 ? Bi1 S3 Bi1 89.9(3) 7_556 7_546 ? Bi1 S3 Pb4 177.7(4) 7_556 7_545 ? Bi1 S3 Pb4 91.54(4) 7_546 7_545 ? Bi1 S3 Pb4 91.54(4) 7_556 7 ? Bi1 S3 Pb4 177.7(4) 7_546 7 ? Pb4 S3 Pb4 87.0(3) 7_545 7 ? Bi1 S3 Pb3 90.8(3) 7_556 . ? Bi1 S3 Pb3 90.8(3) 7_546 . ? Pb4 S3 Pb3 87.4(3) 7_545 . ? Pb4 S3 Pb3 87.4(3) 7 . ? Bi2 S4 Bi2 96.5(3) 7_556 7_546 ? Bi2 S4 Pb5 95.3(3) 7_556 . ? Bi2 S4 Pb5 95.3(3) 7_546 . ? Pb3 S5 Pb3 89.0(3) 7_556 7_546 ? Pb3 S5 Pb6 91.1(3) 7_556 . ? Pb3 S5 Pb6 91.1(3) 7_546 . ? Pb3 S5 Bi2 174.8(4) 7_556 7_546 ? Pb3 S5 Bi2 93.02(4) 7_546 7_546 ? Pb6 S5 Bi2 93.7(2) . 7_546 ? Pb3 S5 Bi2 93.02(4) 7_556 7_556 ? Pb3 S5 Bi2 174.8(4) 7_546 7_556 ? Pb6 S5 Bi2 93.7(2) . 7_556 ? Bi2 S5 Bi2 84.5(3) 7_546 7_556 ? Pb3 S5 Bi1 90.6(2) 7_556 . ? Pb3 S5 Bi1 90.6(2) 7_546 . ? Pb6 S5 Bi1 177.7(4) . . ? Bi2 S5 Bi1 84.6(2) 7_546 . ? Bi2 S5 Bi1 84.6(2) 7_556 . ? Pb4 S6 Pb4 90.8(3) 7_556 7_546 ? Pb4 S6 Pb3 177.3(3) 7_556 7_546 ? Pb4 S6 Pb3 91.92(4) 7_546 7_546 ? Pb4 S6 Pb3 91.92(4) 7_556 7_556 ? Pb4 S6 Pb3 177.3(3) 7_546 7_556 ? Pb3 S6 Pb3 85.3(3) 7_546 7_556 ? Pb4 S6 Pb7 88.0(3) 7_556 . ? Pb4 S6 Pb7 88.0(3) 7_546 . ? Pb3 S6 Pb7 92.0(2) 7_546 . ? Pb3 S6 Pb7 92.0(2) 7_556 . ? Pb5 S7 Pb5 93.7(3) 3 3_545 ? Pb5 S7 Bi8 93.7(3) 3 5_656 ? Pb5 S7 Bi8 93.7(3) 3_545 5_656 ? Pb6 S8 Pb6 88.4(3) 7_546 7_556 ? Pb6 S8 Pb9 89.6(3) 7_546 . ? Pb6 S8 Pb9 89.6(3) 7_556 . ? Pb6 S8 Pb5 177.6(4) 7_546 7_556 ? Pb6 S8 Pb5 93.26(3) 7_556 7_556 ? Pb9 S8 Pb5 92.2(2) . 7_556 ? Pb6 S8 Pb5 93.26(3) 7_546 7_546 ? Pb6 S8 Pb5 177.6(4) 7_556 7_546 ? Pb9 S8 Pb5 92.2(2) . 7_546 ? Pb5 S8 Pb5 85.0(3) 7_556 7_546 ? Pb6 S8 Bi2 92.3(2) 7_546 . ? Pb6 S8 Bi2 92.3(2) 7_556 . ? Pb9 S8 Bi2 177.4(4) . . ? Pb5 S8 Bi2 85.9(2) 7_556 . ? Pb5 S8 Bi2 85.9(2) 7_546 . ? Pb3 S9 Pb7 94.5(3) . 7_546 ? Pb3 S9 Pb7 94.5(3) . 7_556 ? Pb7 S9 Pb7 87.1(3) 7_546 7_556 ? Pb3 S9 Pb6 89.2(3) . 7_556 ? Pb7 S9 Pb6 176.2(4) 7_546 7_556 ? Pb7 S9 Pb6 92.94(4) 7_556 7_556 ? Pb3 S9 Pb6 89.2(3) . 7_546 ? Pb7 S9 Pb6 92.94(4) 7_546 7_546 ? Pb7 S9 Pb6 176.2(4) 7_556 7_546 ? Pb6 S9 Pb6 86.8(3) 7_556 7_546 ? Pb3 S9 Bi10 179.0(4) . . ? Pb7 S9 Bi10 86.2(2) 7_546 . ? Pb7 S9 Bi10 86.2(2) 7_556 . ? Pb6 S9 Bi10 90.0(2) 7_556 . ? Pb6 S9 Bi10 90.0(2) 7_546 . ? Pb4 S10 Pb7 93.6(3) . 7_556 ? Pb4 S10 Pb7 93.6(3) . 7_546 ? Pb7 S10 Pb7 90.3(3) 7_556 7_546 ? Pb4 S10 Pb24 102.8(3) . 7_546 ? Pb7 S10 Pb24 163.3(4) 7_556 7_546 ? Pb7 S10 Pb24 91.99(7) 7_546 7_546 ? Pb4 S10 Pb24 102.8(3) . 7_556 ? Pb7 S10 Pb24 91.99(7) 7_556 7_556 ? Pb7 S10 Pb24 163.3(4) 7_546 7_556 ? Pb24 S10 Pb24 81.2(3) 7_546 7_556 ? Bi8 S11 Bi8 98.7(3) 3_445 3_455 ? Bi8 S11 Pb23 129.74(16) 3_445 . ? Bi8 S11 Pb23 129.74(16) 3_455 . ? Bi8 S11 Pb22 99.4(2) 3_445 . ? Bi8 S11 Pb22 99.4(2) 3_455 . ? Pb23 S11 Pb22 86.7(3) . . ? Pb9 S12 Pb9 89.1(3) 7_556 7_546 ? Pb9 S12 Pb5 95.2(2) 7_556 . ? Pb9 S12 Pb5 95.2(2) 7_546 . ? Pb9 S12 Bi8 175.9(4) 7_556 7_546 ? Pb9 S12 Bi8 92.36(4) 7_546 7_546 ? Pb5 S12 Bi8 88.5(3) . 7_546 ? Pb9 S12 Bi8 92.36(4) 7_556 7_556 ? Pb9 S12 Bi8 175.9(4) 7_546 7_556 ? Pb5 S12 Bi8 88.5(3) . 7_556 ? Bi8 S12 Bi8 85.9(3) 7_546 7_556 ? Pb9 S12 Bi11 88.8(3) 7_556 . ? Pb9 S12 Bi11 88.8(3) 7_546 . ? Pb5 S12 Bi11 174.3(4) . . ? Bi8 S12 Bi11 87.3(2) 7_546 . ? Bi8 S12 Bi11 87.3(2) 7_556 . ? Pb6 S13 Pb9 90.0(3) . 7_546 ? Pb6 S13 Pb9 90.0(3) . 7_556 ? Pb9 S13 Pb9 87.6(3) 7_546 7_556 ? Pb6 S13 Bi10 94.7(2) . 7_556 ? Pb9 S13 Bi10 175.3(4) 7_546 7_556 ? Pb9 S13 Bi10 92.84(4) 7_556 7_556 ? Pb6 S13 Bi10 94.7(2) . 7_546 ? Pb9 S13 Bi10 92.84(4) 7_546 7_546 ? Pb9 S13 Bi10 175.3(4) 7_556 7_546 ? Bi10 S13 Bi10 86.4(3) 7_556 7_546 ? Pb6 S13 Bi12 177.7(4) . . ? Pb9 S13 Bi12 88.4(2) 7_546 . ? Pb9 S13 Bi12 88.4(2) 7_556 . ? Bi10 S13 Bi12 86.9(3) 7_556 . ? Bi10 S13 Bi12 86.9(3) 7_546 . ? Bi10 S14 Bi10 95.7(4) 7_546 7_556 ? Bi10 S14 Pb7 96.2(3) 7_546 . ? Bi10 S14 Pb7 96.2(3) 7_556 . ? Bi10 S14 Bi17 124.4(3) 7_546 . ? Bi10 S14 Bi17 124.4(3) 7_556 . ? Pb7 S14 Bi17 113.6(4) . . ? Bi11 S15 Bi11 94.8(3) 7_546 7_556 ? Bi11 S15 Bi8 97.0(2) 7_546 . ? Bi11 S15 Bi8 97.0(2) 7_556 . ? Bi12 S16 Bi12 88.9(3) 7_546 7_556 ? Bi12 S16 Bi11 176.6(4) 7_546 7_556 ? Bi12 S16 Bi11 92.29(4) 7_556 7_556 ? Bi12 S16 Bi11 92.29(4) 7_546 7_546 ? Bi12 S16 Bi11 176.6(4) 7_556 7_546 ? Bi11 S16 Bi11 86.4(3) 7_556 7_546 ? Bi12 S16 Pb9 89.1(2) 7_546 . ? Bi12 S16 Pb9 89.1(2) 7_556 . ? Bi11 S16 Pb9 87.8(3) 7_556 . ? Bi11 S16 Pb9 87.8(3) 7_546 . ? Bi12 S17 Bi12 93.3(3) 7_556 7_546 ? Bi12 S17 Bi10 96.4(2) 7_556 . ? Bi12 S17 Bi10 96.4(2) 7_546 . ? Bi13 S18 Bi13 95.5(3) 7_556 7_546 ? Bi13 S18 Pb25 95.4(3) 7_556 . ? Bi13 S18 Pb25 95.4(3) 7_546 . ? Bi13 S18 Bi16 95.6(3) 7_556 . ? Bi13 S18 Bi16 95.6(3) 7_546 . ? Pb25 S18 Bi16 163.6(4) . . ? Pb14 S19 Pb14 88.2(3) 7_556 7_546 ? Pb14 S19 Bi13 174.5(3) 7_556 7_546 ? Pb14 S19 Bi13 92.66(4) 7_546 7_546 ? Pb14 S19 Bi13 92.66(4) 7_556 7_556 ? Pb14 S19 Bi13 174.5(3) 7_546 7_556 ? Bi13 S19 Bi13 86.0(3) 7_546 7_556 ? Pb14 S19 Pb23 97.2(2) 7_556 . ? Pb14 S19 Pb23 97.2(2) 7_546 . ? Bi13 S19 Pb23 88.1(2) 7_546 . ? Bi13 S19 Pb23 88.1(2) 7_556 . ? Pb14 S19 Bi15 90.7(2) 7_556 . ? Pb14 S19 Bi15 90.7(2) 7_546 . ? Bi13 S19 Bi15 83.9(2) 7_546 . ? Bi13 S19 Bi15 83.9(2) 7_556 . ? Pb23 S19 Bi15 169.0(4) . . ? Cu3 S20 Bi15 78.1(2) 5_656 7_556 ? Cu3 S20 Bi15 78.1(2) 5_656 7_546 ? Bi15 S20 Bi15 90.9(3) 7_556 7_546 ? Cu3 S20 Pb14 174.2(4) 5_656 . ? Bi15 S20 Pb14 97.8(2) 7_556 . ? Bi15 S20 Pb14 97.8(2) 7_546 . ? Cu3 S20 Pb14 81.4(2) 5_656 7_546 ? Bi15 S20 Pb14 159.1(3) 7_556 7_546 ? Bi15 S20 Pb14 88.99(7) 7_546 7_546 ? Pb14 S20 Pb14 102.9(2) . 7_546 ? Cu3 S20 Pb14 81.4(2) 5_656 7_556 ? Bi15 S20 Pb14 88.99(7) 7_556 7_556 ? Bi15 S20 Pb14 159.1(3) 7_546 7_556 ? Pb14 S20 Pb14 102.9(2) . 7_556 ? Pb14 S20 Pb14 83.8(3) 7_546 7_556 ? Bi15 S21 Bi15 92.6(3) 7_546 7_556 ? Bi15 S21 Ag 175.1(4) 7_546 7_556 ? Bi15 S21 Ag 90.11(5) 7_556 7_556 ? Bi15 S21 Bi16 175.1(4) 7_546 7_556 ? Bi15 S21 Bi16 90.11(5) 7_556 7_556 ? Ag S21 Bi16 0.00(8) 7_556 7_556 ? Bi15 S21 Ag 90.11(5) 7_546 7_546 ? Bi15 S21 Ag 175.1(4) 7_556 7_546 ? Ag S21 Ag 86.9(3) 7_556 7_546 ? Bi16 S21 Ag 86.9(3) 7_556 7_546 ? Bi15 S21 Bi16 90.11(5) 7_546 7_546 ? Bi15 S21 Bi16 175.1(4) 7_556 7_546 ? Ag S21 Bi16 86.9(3) 7_556 7_546 ? Bi16 S21 Bi16 86.9(3) 7_556 7_546 ? Ag S21 Bi16 0.00(8) 7_546 7_546 ? Bi15 S21 Bi13 87.4(3) 7_546 . ? Bi15 S21 Bi13 87.4(3) 7_556 . ? Ag S21 Bi13 88.6(2) 7_556 . ? Bi16 S21 Bi13 88.6(2) 7_556 . ? Ag S21 Bi13 88.6(2) 7_546 . ? Bi16 S21 Bi13 88.6(2) 7_546 . ? Cu S22 Ag 96.4(3) . 7_546 ? Cu S22 Bi16 96.4(3) . 7_546 ? Ag S22 Bi16 0.00(9) 7_546 7_546 ? Cu S22 Ag 96.4(3) . 7_556 ? Ag S22 Ag 94.6(3) 7_546 7_556 ? Bi16 S22 Ag 94.6(3) 7_546 7_556 ? Cu S22 Bi16 96.4(3) . 7_556 ? Ag S22 Bi16 94.6(3) 7_546 7_556 ? Bi16 S22 Bi16 94.6(3) 7_546 7_556 ? Ag S22 Bi16 0.00(9) 7_556 7_556 ? Cu S22 Pb25 109.2(3) . 3_545 ? Ag S22 Pb25 85.16(10) 7_546 3_545 ? Bi16 S22 Pb25 85.16(10) 7_546 3_545 ? Ag S22 Pb25 154.2(4) 7_556 3_545 ? Bi16 S22 Pb25 154.2(4) 7_556 3_545 ? Cu S22 Pb25 109.2(3) . 3 ? Ag S22 Pb25 154.2(4) 7_546 3 ? Bi16 S22 Pb25 154.2(4) 7_546 3 ? Ag S22 Pb25 85.16(10) 7_556 3 ? Bi16 S22 Pb25 85.16(10) 7_556 3 ? Pb25 S22 Pb25 84.1(3) 3_545 3 ? Bi20 S23 Bi17 98.8(3) . 7_556 ? Bi20 S23 Bi17 98.8(3) . 7_546 ? Bi17 S23 Bi17 90.9(3) 7_556 7_546 ? Bi21 S24 Bi17 93.6(3) . 7_546 ? Bi21 S24 Bi17 93.6(3) . 7_556 ? Bi17 S24 Bi17 89.9(3) 7_546 7_556 ? Bi21 S24 Pb18 95.3(3) . 7_556 ? Bi17 S24 Pb18 170.2(4) 7_546 7_556 ? Bi17 S24 Pb18 93.58(5) 7_556 7_556 ? Bi21 S24 Pb18 95.3(3) . 7_546 ? Bi17 S24 Pb18 93.58(5) 7_546 7_546 ? Bi17 S24 Pb18 170.2(4) 7_556 7_546 ? Pb18 S24 Pb18 81.6(2) 7_556 7_546 ? Cu2 S25 Pb18 85.4(3) . 7_546 ? Cu2 S25 Pb18 85.4(3) . 7_556 ? Pb18 S25 Pb18 89.4(3) 7_546 7_556 ? Cu2 S25 Bi19 83.7(3) . 7_556 ? Pb18 S25 Bi19 169.0(4) 7_546 7_556 ? Pb18 S25 Bi19 91.45(5) 7_556 7_556 ? Cu2 S25 Bi19 83.7(3) . 7_546 ? Pb18 S25 Bi19 91.45(5) 7_546 7_546 ? Pb18 S25 Bi19 169.0(4) 7_556 7_546 ? Bi19 S25 Bi19 85.7(3) 7_556 7_546 ? Cu3 S26 Bi19 93.3(3) 5_656 7_546 ? Cu3 S26 Bi19 93.3(3) 5_656 7_556 ? Bi19 S26 Bi19 95.1(3) 7_546 7_556 ? Cu3 S26 Pb23 165.3(5) 5_656 . ? Bi19 S26 Pb23 96.6(3) 7_546 . ? Bi19 S26 Pb23 96.6(3) 7_556 . ? Cu1 S27 Cu1 70.8(3) 5_656 1_556 ? Cu1 S27 Bi20 104.1(3) 5_656 7_546 ? Cu1 S27 Bi20 131.10(16) 1_556 7_546 ? Cu1 S27 Bi20 104.1(3) 5_656 7_556 ? Cu1 S27 Bi20 131.10(16) 1_556 7_556 ? Bi20 S27 Bi20 97.7(3) 7_546 7_556 ? Bi17 S28 Bi21 93.0(3) . 7_546 ? Bi17 S28 Bi21 93.0(3) . 7_556 ? Bi21 S28 Bi21 89.1(3) 7_546 7_556 ? Bi17 S28 Bi20 93.7(3) . 7_556 ? Bi21 S28 Bi20 172.4(4) 7_546 7_556 ? Bi21 S28 Bi20 94.02(5) 7_556 7_556 ? Bi17 S28 Bi20 93.7(3) . 7_546 ? Bi21 S28 Bi20 94.02(5) 7_546 7_546 ? Bi21 S28 Bi20 172.4(4) 7_556 7_546 ? Bi20 S28 Bi20 82.1(2) 7_556 7_546 ? Pb18 S29 Bi21 101.1(2) . 7_556 ? Pb18 S29 Bi21 101.1(2) . 7_546 ? Bi21 S29 Bi21 92.3(3) 7_556 7_546 ? Bi19 S30 Pb22 107.0(3) . 7_556 ? Bi19 S30 Pb22 107.0(3) . 7_546 ? Pb22 S30 Pb22 89.2(3) 7_556 7_546 ? Bi19 S30 Pb23 101.0(3) . 7_546 ? Pb22 S30 Pb23 151.6(4) 7_556 7_546 ? Pb22 S30 Pb23 87.10(10) 7_546 7_546 ? Bi19 S30 Pb23 101.0(3) . 7_556 ? Pb22 S30 Pb23 87.10(10) 7_556 7_556 ? Pb22 S30 Pb23 151.6(4) 7_546 7_556 ? Pb23 S30 Pb23 83.0(2) 7_546 7_556 ? Bi13 S31 Pb23 99.4(3) . 7_546 ? Bi13 S31 Pb23 99.4(3) . 7_556 ? Pb23 S31 Pb23 88.1(3) 7_546 7_556 ? Bi13 S31 Pb25 96.1(2) . 7_556 ? Pb23 S31 Pb25 164.4(4) 7_546 7_556 ? Pb23 S31 Pb25 91.02(7) 7_556 7_556 ? Bi13 S31 Pb25 96.1(2) . 7_546 ? Pb23 S31 Pb25 91.02(7) 7_546 7_546 ? Pb23 S31 Pb25 164.4(4) 7_556 7_546 ? Pb25 S31 Pb25 85.7(3) 7_556 7_546 ? Cu3 S32 Cu3 121.0(5) 3_455 3_445 ? Cu3 S32 Bi15 88.9(3) 3_455 . ? Cu3 S32 Bi15 88.9(3) 3_445 . ? Cu3 S32 Pb26 157.9(4) 3_455 7_546 ? Cu3 S32 Pb26 77.97(17) 3_445 7_546 ? Bi15 S32 Pb26 103.7(3) . 7_546 ? Cu3 S32 Pb26 77.97(17) 3_455 7_556 ? Cu3 S32 Pb26 157.9(4) 3_445 7_556 ? Bi15 S32 Pb26 103.7(3) . 7_556 ? Pb26 S32 Pb26 81.4(2) 7_546 7_556 ? Bi11 S33 Bi16 126.2(5) . . ? Bi11 S33 Pb26 105.4(3) . 7_556 ? Bi16 S33 Pb26 111.9(3) . 7_556 ? Bi11 S33 Pb26 105.4(3) . 7_546 ? Bi16 S33 Pb26 111.9(3) . 7_546 ? Pb26 S33 Pb26 89.7(4) 7_556 7_546 ? Cu2 S34 Cu2 122.4(5) 7_556 7_546 ? Cu2 S34 Bi12 94.1(3) 7_556 . ? Cu2 S34 Bi12 94.1(3) 7_546 . ? _diffrn_measured_fraction_theta_max 0.926 _diffrn_reflns_theta_full 28.36 _diffrn_measured_fraction_theta_full 0.926 _refine_diff_density_max 8.481 _refine_diff_density_min -5.943 _refine_diff_density_rms 0.910